Magnetism: Molecules to Materials IV

摘要: Preface. 1 Metallocenium Salts of Radical Anion Bis(Dichalcogenate) Metalates (Vasco Gama and Maria Teresa Duarte). 1.1 Introduction. 1.2 Basic Structural Motifs. 1.3 Solid-state Structures Magnetic Behavior. 1.4 Summary Conclusions. References. 2 Chiral Molecule-Based Magnets (Katsuya Inoue, Shin-ichi Ohkoshi, Hiroyuki Imai). 2.1 2.2 Physical Optical Properties or Noncentrosymmetric Materials. 2.3 Nitroxide-manganese Based Magnets. 2.4 Two- Three-dimensional Cyanide Bridged 2.5 SHG-active Prussian Blue Films. 2.6 Conclusion. 3 Cooperative Behavior in Metal-Dicyanamide Complexes (Jamie L. Manson). 3.1 3.2 "Binary" alpha-M(dca)2 3.3 beta-M(dca)2 3.4 Mixed-anion M(dca)(tcm). 3.5 Polymeric 2D (cat)M(dca)34As, Fe(bipy)3. 3.6 Heteroleptic M(dca)2L 3.7 Dicyanophosphide: A Phosphorus-containing Analog Dicyanamide. 3.8 Conclusions Future Prospects. 4 Molecular Materials Combining Conducting (Peter Day Eugenio Coronado). 4.1 4.2 Interest Molecular-based 4.3 Ions Charge Transfer Salts. 4.4 5 Lanthanide Exchange Coupled Systems (Jean-Pascal Sutter Myrtil Kahn). 5.1 5.2 Compounds Involving Gd(III). 5.3 Superexchange Mediated by Ln(III) Ions. 5.4 with a First-order Orbital Momentum. 5.5 Concluding Remarks. 6 Monte Carlo Simulation: Tool to Analyse (Joan Cano Yves Journaux). 6.1 6.2 Method. 6.3 Regular Infinite Networks. 6.4 Alternating Chains. 6.5 Finite Systems. 6.6 Exact Laws versus MC Simulations. 6.7 Some Complex Examples. 6.8 7 Metallocene-based (Gordon T. Yee Joel S. Miller). 7.1 7.2 Electrochemical Neutral Decamethylmetallocenes Decamethylmetallocenium Cations Paired Diamagnetic Anions. 7.3 Preparation Electron 7.4 Crystal ET 7.5 Tetracyanoethylene (Scheme 7.2). 7.6 Dimethyl Dicyanofumarate Diethyl 7.7 2,3-Dichloro-5,6-dicyanoquinone Related Compounds. 7.8 2,3-Dicyano-1,4-naphthoquinone 7.9 7,7,8,8-Tetracyano-p-quinodimethane 7.10 2,5-Dimethyl-N,N'-dicyanoquinodiimine 7.11 1,4,9,10-Anthracenetetrone 7.12 Cyano Perfluoromethyl Ethylenedithiolato Metalate 7.13 Benzenedithiolates Ethylenedithiolates. 7.14 Additional Dithiolate 7.15 Bis(trifluoromethyl)ethylenediselenato Nickelate 7.16 Other Acceptors that Support Ferromagnetic Coupling, but not Long-range Order above ~2K. 7.17 Metallocenes Species as Donors. 7.18 Muon Spin Relaxation Spectroscopy. 7.19 Mossbauer 7.20 Density Distribution from Calculations Neutron Diffraction Data. 7.21 Dimensionality the System Evidence for Phase Transition. 7.22 The Controversy Around Mechanism Coupling 7.23 Trends. 7.24 Research Opportunities. 8 Nanoporous (Daniel Maspoch, Daniel Ruiz-Molina, Jaume Veciana). 8.1 8.2 Inorganic Hybrid 8.3 Coordination Polymers. 8.4 Perspectives. 9 Analogs (Michel Verdaguer Gregory Girolami). 9.1 9.2 (PBA), Brief History, Synthesis Structure. 9.3 Blues (MPB). 9.4 High TC (the Experimental Race Curie Temperatures). 9.5 Prospects New 9.6 Conclusion: 300 Years Old "Inorganic Evergreen". 10 Scaling Theory Applied Low Dimensional (Jean Souletie, Pierre Rabu, Marc Drillon). 10.1 10.2 Non-critical-scaling: Solutions Model. 10.3 Universality Classes Lower Critical Dimensionality. 10.4 Transition Layered 10.5 Description Heisenberg 10.6 Application Spin-1 Haldane Chain. 10.7 Index.