Heavy Ozone--A Difficult Puzzle to Solve
作者： D. Krankowsky , K. Mauersberger
DOI: 10.1126/SCIENCE.274.5291.1324
关键词:
摘要: Although not abundant, ozone is one of the most important constituents atmosphere. The isotopic variants ozone, which a symmetric triangular molecule made three oxygen atoms, are difficult to explain by theoretical analysis. In their Perspective, Krankowsky and Mauersberger discuss results published in same issue Gellene ([p. 1344][1]) that shed light on mechanisms responsible for heavier isotopes ozone. [1]: /lookup/doi/10.1126/science.274.5291.1344
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K. Mauersberger, J. Morton, B. Schueler, J. Stehr, S. M. Anderson, Multi-isotope study of ozone: Implications for the heavy ozone anomaly Geophysical Research Letters. ,vol. 20, pp. 1031- 1034 ,(1993) , 10.1029/93GL01080
John E. Heidenreich, Mark H. Thiemens, A non‐mass‐dependent oxygen isotope effect in the production of ozone from molecular oxygen: The role of molecular symmetry in isotope chemistry The Journal of Chemical Physics. ,vol. 84, pp. 2129- 2136 ,(1986) , 10.1063/1.450373
B. Schueler, J. Morton, K. Mauersberger, Measurement of isotopic abundances in collected stratospheric ozone samples Geophysical Research Letters. ,vol. 17, pp. 1295- 1298 ,(1990) , 10.1029/GL017I009P01295
K. Mauersberger, Ozone isotope measurements in the stratosphere Geophysical Research Letters. ,vol. 14, pp. 80- 83 ,(1987) , 10.1029/GL014I001P00080
James J. Valentini, Mass‐independent isotopic fractionation in nonadiabatic molecular collisions Journal of Chemical Physics. ,vol. 86, pp. 6757- 6765 ,(1987) , 10.1063/1.452375
M. James Salinger, John Hay, Ron McGann, Blair Fitzharris, Southwest Pacific temperatures: Diurnal and seasonal trends Geophysical Research Letters. ,vol. 20, pp. 935- 938 ,(1993) , 10.1029/93GL01113
G. I. Gellene, An Explanation for Symmetry-Induced Isotopic Fractionation in Ozone Science. ,vol. 274, pp. 1344- 1346 ,(1996) , 10.1126/SCIENCE.274.5291.1344
Konrad Mauersberger, Measurement of heavy ozone in the stratosphere Geophysical Research Letters. ,vol. 8, pp. 935- 937 ,(1981) , 10.1029/GL008I008P00935
Jack A. Kaye, Theoretical analysis of isotope effects on ozone formation in oxygen photochemistry Journal of Geophysical Research. ,vol. 91, pp. 7865- 7874 ,(1986) , 10.1029/JD091ID07P07865
Arndt Meier, Justus Notholt, Determination of the isotopic abundances of heavy O3as observed in Arctic ground-based FTIR-spectra Geophysical Research Letters. ,vol. 23, pp. 551- 554 ,(1996) , 10.1029/96GL00374