Analysis of velocity-mapped ion images from high-resolution crossed-beam scattering experiments: a tutorial review.

作者: Alexander von Zastrow , Jolijn Onvlee , David H. Parker , Sebastiaan Y.T. van de Meerakker

DOI: 10.1140/EPJTI/S40485-015-0020-Z

关键词:

摘要: A Stark decelerator produces beams of molecules with high quantum state purity, and small spatial, temporal velocity spreads. These tamed molecular are ideally suited for high-resolution crossed beam scattering experiments. When map imaging is used, the allows measurement images unprecedented radial sharpness angular resolution. Differential cross sections must be extracted from these extreme care, however. Common image analysis techniques that used throughout in experiments can result systematic errors, particular determination collision energy, allocation angles to observed peaks distribution. Using a data set on inelastic collisions velocity-controlled NO radicals Ne atoms, we describe challenges met by resolution, present methods mitigate or overcome them.

参考文章(28)
Imaging in chemical dynamics American Chemical Society. ,(2000) , 10.1021/BK-2001-0770
Jolijn Onvlee, Sjoerd N Vogels, Ad van der Avoird, Gerrit C Groenenboom, Sebastiaan Y T van de Meerakker, Resolving rainbows with superimposed diffraction oscillations in NO + rare gas scattering: experiment and theory New Journal of Physics. ,vol. 17, pp. 055019- ,(2015) , 10.1088/1367-2630/17/5/055019
Chris J Eyles, Mark Brouard, Helen Chadwick, Balazs Hornung, Bethan Nichols, C-H Yang, J Kłos, FJ Aoiz, Arjan Gijsbertsen, AE Wiskerke, S Stolte, None, Fully Λ-doublet resolved state-to-state differential cross-sections for the inelastic scattering of NO(X) with Ar Physical Chemistry Chemical Physics. ,vol. 14, pp. 5403- 5419 ,(2012) , 10.1039/C2CP23258H
L. Scharfenberg, K. B. Gubbels, M. Kirste, G. C. Groenenboom, A. van der Avoird, G. Meijer, S. Y. T. van de Meerakker, Scattering of Stark-decelerated OH radicals with rare gas atoms European Physical Journal D. ,vol. 65, pp. 189- 198 ,(2011) , 10.1140/EPJD/E2011-20009-4
Alexander von Zastrow, Jolijn Onvlee, Sjoerd N. Vogels, Gerrit C. Groenenboom, Ad van der Avoird, Sebastiaan Y. T. van de Meerakker, State-resolved diffraction oscillations imaged for inelastic collisions of NO radicals with He, Ne and Ar Nature Chemistry. ,vol. 6, pp. 216- 221 ,(2014) , 10.1038/NCHEM.1860
M. L. V. Pitteway, Algorithm for drawing ellipses or hyperbolae with a digital plotter The Computer Journal. ,vol. 10, pp. 282- 289 ,(1967) , 10.1093/COMJNL/10.3.282
M. Brouard, H. Chadwick, C. J. Eyles, B. Hornung, B. Nichols, F. J. Aoiz, P. G. Jambrina, S. Stolte, M. P. de Miranda, Rotational alignment effects in NO(X) + Ar inelastic collisions: A theoretical study Journal of Chemical Physics. ,vol. 138, pp. 104309- 104309 ,(2013) , 10.1063/1.4792158
B. Yan, P. F. H. Claus, B. G. M. van Oorschot, L. Gerritsen, A. T. J. B. Eppink, S. Y. T. van de Meerakker, D. H. Parker, A new high intensity and short-pulse molecular beam valve Review of Scientific Instruments. ,vol. 84, pp. 023102- ,(2013) , 10.1063/1.4790176