Charge transport in solid polymer matrixes with redox centers

摘要: Abstract Charge transport in solid polymer matrixes with redox centers their ground and photoexcited states was reviewed. the state can be investigated mainly by electrochemical methods, which provides information about integrated charge propagation matrix. a photochemical methods providing on one single transfer step at an excited state. In state, charges are transported molecular diffusion, hopping between molecules, or combination of former latter. Methods to study mechanism were described, typical examples for each given. An important factor determine concluded interaction molecule Typical distance presented. This is near 1.3 nm without mediator (molecule's center-to-center), 40–100% longer presence molecule. Electrocatalysis polymer–redox coated electrode its analysis also mentioned. such as laser flash photolysis luminescence quenching. The here both dynamic static; taking place diffusion collision molecules latter diffusion. Various models presented analyze matrixes, takes static mechanism, similar that state; around nearly twice Combined systems briefly reviewed, some approaches more photoelectric devices introduced.