Development and Characterization of "Green Open-Cell Polyurethane Foams" with Reduced Flammability.

作者: Maria Kurańska , Hynek Beneš , Kamila Sałasińska , Aleksander Prociak , Elżbieta Malewska

DOI: 10.3390/MA13235459

关键词:

摘要: This work presents the cell structure and selected properties of polyurethane (PUR) foams, based on two types hydroxylated used cooking oil additionally modified with three different flame retardants. Bio-polyols from municipal waste chemical structures were obtained by transesterification triethanolamine (UCO_TEA) diethylene glycol (UCO_DEG). Next, these bio-polyols to prepare open-cell foams very low apparent densities for thermal insulation applications. In order obtain reduced flammability, PUR systems amounts (10–30 parts per hundred polyol weight—php) retardants: TCPP (tris(1-chloro-2-propyl)phosphate), TEP (triethyl phosphate), DMPP (dimethyl propylphosphonate). The retardants caused a decrease formulations reactivity. all comparable in range 12–15 kg/m3. lowest coefficients conductivity measured DMPP. values heat release rate found UCO_TEA UCO_DEG that 30 php

参考文章(30)
Sabyasachi Gaan, Shuyu Liang, Henri Mispreuve, Heribert Perler, Reinold Naescher, Matthias Neisius, Flame retardant flexible polyurethane foams from novel DOPO-phosphonamidate additives Polymer Degradation and Stability. ,vol. 113, pp. 180- 188 ,(2015) , 10.1016/J.POLYMDEGRADSTAB.2015.01.007
Aruna Palanisamy, M. S. L. Karuna, T. Satyavani, D. B. Rohini Kumar, Development and Characterization of Water-Blown Polyurethane Foams from Diethanolamides of Karanja Oil Journal of the American Oil Chemists' Society. ,vol. 88, pp. 541- 549 ,(2011) , 10.1007/S11746-010-1694-7
Athanasia A. Septevani, David A.C. Evans, Celine Chaleat, Darren J. Martin, Pratheep K. Annamalai, A systematic study substituting polyether polyol with palm kernel oil based polyester polyol in rigid polyurethane foam Industrial Crops and Products. ,vol. 66, pp. 16- 26 ,(2015) , 10.1016/J.INDCROP.2014.11.053
Meng Zhang, Jinwen Zhang, Shuigen Chen, Yonghong Zhou, Synthesis and fire properties of rigid polyurethane foams made from a polyol derived from melamine and cardanol Polymer Degradation and Stability. ,vol. 110, pp. 27- 34 ,(2014) , 10.1016/J.POLYMDEGRADSTAB.2014.08.009
Xilei Chen, Lili Huo, Chuanmei Jiao, Shaoxiang Li, TG–FTIR characterization of volatile compounds from flame retardant polyurethane foams materials Journal of Analytical and Applied Pyrolysis. ,vol. 100, pp. 186- 191 ,(2013) , 10.1016/J.JAAP.2012.12.017
Łukasz Piszczyk, Michał Strankowski, Magdalena Danowska, Józef T. Haponiuk, Maria Gazda, Preparation and characterization of rigid polyurethane–polyglycerol nanocomposite foams European Polymer Journal. ,vol. 48, pp. 1726- 1733 ,(2012) , 10.1016/J.EURPOLYMJ.2012.07.001
A. Lorenzetti, M. Modesti, S. Besco, D. Hrelja, S. Donadi, Influence of phosphorus valency on thermal behaviour of flame retarded polyurethane foams Polymer Degradation and Stability. ,vol. 96, pp. 1455- 1461 ,(2011) , 10.1016/J.POLYMDEGRADSTAB.2011.05.012
Maria Kurańska, Aleksander Prociak, The influence of rapeseed oil-based polyols on the foaming process of rigid polyurethane foams Industrial Crops and Products. ,vol. 89, pp. 182- 187 ,(2016) , 10.1016/J.INDCROP.2016.05.016
Jia-Jia He, Lin Jiang, Jin-Hua Sun, Siuming Lo, Thermal degradation study of pure rigid polyurethane in oxidative and non-oxidative atmospheres Journal of Analytical and Applied Pyrolysis. ,vol. 120, pp. 269- 283 ,(2016) , 10.1016/J.JAAP.2016.05.015
Wang Xi, Lijun Qian, Zhigang Huang, Yanfang Cao, Linjie Li, Continuous flame-retardant actions of two phosphate esters with expandable graphite in rigid polyurethane foams Polymer Degradation and Stability. ,vol. 130, pp. 97- 102 ,(2016) , 10.1016/J.POLYMDEGRADSTAB.2016.06.003