An unprecedented {CuII14TeIV10} core incorporated in a 36-tungsto-4-silicate polyoxometalate with visible light-driven catalytic hydrogen evolution activity
作者： Wei-Chao Chen , Si-Tong Wu , Chao Qin , Xin-Long Wang , Kui-Zhan Shao
DOI: 10.1039/C8DT03658F
关键词:
摘要: We report an unprecedented {CuII14TeIV10} core containing the novel μ,μ-/μ6-TeIVO32− mode and TeIVO44− embedded within a 36-tungsto-4-silicate POT shell, which constitutes first example of tellurous copper cluster in POMs. The structure-stabilizing templating effects tellurite anions are crucial for this assembly. Moreover, its visible light-driven catalytic H2 evolution activity related quenching mechanism demonstrated, extensive stability studies presented.
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