II. Calculation of Energy of H3+Ion

摘要: The potential energies for linear symmetrical configurations of H3+ have been calculated by the same methods used in previous paper (I). at minimum kcal./mole and corresponding distances between neighboring atoms Bohr radii various approximations are: Heitler−London−91.92 at 2.00;H.L. plus polar−108.64 at 2.00;Wang Approx.−130.89 at 1.55;Wang polar−155.35 at 1.52. It follows from use variational method that energy binding a proton to H2 is greater than 46.8 kcal./mole. If we Wang polar approximation obtain this 63.11 reaction H2++H2→H3++H may be exothermal cannot more slightly endothermal.