Asymmetrische Katalysen, 58. Mitt.: Enantioselektive S - H- und C - H-Insertionen mit optisch aktiven Rh(II)- und Cu(II)-Katalysatoren
作者： Henri Brunner , Konrad Wutz , Michael P. Doyle
DOI: 10.1007/BF00808368
关键词:
摘要: The substrates for the S - H insertion reaction were azibutanone2 and thiophenol3. Methyl 2-diazo-3-oxo-heptane-carboxylate26 was used as substrate in an intramolecular C insertion. Both reactions carried out enantioselectively presence of optically active rhodium(II) copper(II) catalysts. For optical inductions up to 13.8%ee 14%ee achieved.
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