THE STABILITY OF MICROEMULSION SYSTEMS
作者： W. Gerbacia , H.L. Rosano , J.H. Whittam
DOI: 10.1016/B978-0-12-404502-6.50025-1
关键词:
摘要: Microemulsions are considered as thermodynamically unstable systems and distinct from stable swollen micellar solutions. The stability of microemulsion is assumed to arise the presence surfactant-cosurfactant-solvent film surrounding oil droplets. An osmotic effect be operable energy barriers coalescence calculated by using regular solution concepts describe interactions in interphase between two droplets close approach. this model seen high enough explain long term these systems. separation one system was observed for verification.
sci-hub.st 参考文章(14)
E. W. Fischer, Elektronenmikroskopische Untersuchungen zur Stabilität von Suspensionen in makromolekularen Lösungen Colloid and Polymer Science. ,vol. 160, pp. 120- 141 ,(1958) , 10.1007/BF01503288
J. H. Schulman, T. S. McRoberts, On the structure of transparent water and oil dispersions (solubilised oils) Transactions of The Faraday Society. ,vol. 42, ,(1946) , 10.1039/TF946420B165
Marjorie J. Vold, The effect of adsorption on the van der waals interaction of spherical colloidal particles Journal of Colloid Science. ,vol. 16, pp. 1- 12 ,(1961) , 10.1016/0095-8522(61)90057-5
Walther Stoeckenius, Jack H. Schulman, Leon M. Prince, The structure of myelin figures and microemulsions as observed with the electron microscope Colloid and Polymer Science. ,vol. 169, pp. 170- 180 ,(1960) , 10.1007/BF01502567
W. E. Gerbacia, H. L. Rosano, M. Zajac, Solubilization in aqueous mixed micellar solutions: Water-potassium oleate-1-pentanol-benzene Journal of the American Oil Chemists' Society. ,vol. 53, pp. 101- 104 ,(1976) , 10.1007/BF02635958
Pranab Bagchi, Theory of stabilization of spherical colloidal particles by nonionic polymers Journal of Colloid and Interface Science. ,vol. 47, pp. 86- 99 ,(1974) , 10.1016/0021-9797(74)90082-4
F. Th. Hesselink, A. Vrij, J. Th. G. Overbeek, Theory of the stabilization of dispersions by adsorbed macromolecules. II. Interaction between two flat particles The Journal of Physical Chemistry. ,vol. 75, pp. 2094- 2103 ,(1971) , 10.1021/J100683A005
T. P. HOAR, J. H. SCHULMAN, Transparent Water-in-Oil Dispersions: the Oleopathic Hydro-Micelle Nature. ,vol. 152, pp. 102- 103 ,(1943) , 10.1038/152102A0
George. Scatchard, Equilibria in Non-electrolyte Solutions in Relation to the Vapor Pressures and Densities of the Components. Chemical Reviews. ,vol. 8, pp. 321- 333 ,(1931) , 10.1021/CR60030A010
J.H Schulman, D.P Riley, X-ray investigation of the structure of transparent oil-water disperse systems. I Journal of Colloid Science. ,vol. 3, pp. 383- 405 ,(1948) , 10.1016/0095-8522(48)90024-5