Photosensitizing porphyrin–triazine compound for bulk heterojunction solar cells
作者： Aritat Luechai , Jacek Gasiorowski , Amorn Petsom , Helmut Neugebauer , Niyazi Serdar Sariciftci
DOI: 10.1039/C2JM33840H
关键词:
摘要: This report describes the synthesis of a novel porphyrin–triazine compound bearing three porphyrin macrocycles connected to each other via triazine central unit, and investigation its properties for possible use in bulk heterojunction solar cells (BHJ-SCs). The serve as light harvesting antennae, while triazines have been widely known be charge extracting promoters. According cyclic voltammetric studies, Highest Occupied Molecular Orbital (HOMO) Lowest Unoccupied (LUMO) energy levels target were estimated at −5.4 −3.5 eV versus vacuum, respectively. Photoluminescence measurements blended films phenyl-C61-butyric acid methyl ester (PCBM) or poly(3-hexylthiophene) (P3HT) indicated that transfer was when used an electron donor together with PCBM acceptor. Additionally, surface morphology different donor:acceptor ratios investigated by atomic force microscopy (AFM). Upon variation weight ratio thickness organic layer, short circuit current density (JSC) BHJ-SCs fabricated herein improved up approximately 2.25 mA cm−2.
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sci-hub.se 参考文章(112)
Quan Yuan Hu, Wei Xin Lu, Hong Ding Tang, Herman H. Y. Sung, Ting Bin Wen, Ian D. Williams, George K. L. Wong, Zhenyang Lin, Guochen Jia, Synthesis and photophysical properties of trimetallic acetylide complexes with a 1,3,5-triazine core Organometallics. ,vol. 24, pp. 3966- 3973 ,(2005) , 10.1021/OM0502133
Hiroshi Imahori, Tomokazu Umeyama, Seigo Ito, Large π-Aromatic Molecules as Potential Sensitizers for Highly Efficient Dye-Sensitized Solar Cells Accounts of Chemical Research. ,vol. 42, pp. 1809- 1818 ,(2009) , 10.1021/AR900034T
Takashi Murase, Makoto Fujita, Highly blue luminescent triazine-amine conjugated oligomers. Journal of Organic Chemistry. ,vol. 70, pp. 9269- 9278 ,(2005) , 10.1021/JO051268H
Ralf Fink, Yvonne Heischkel, Mukundan Thelakkat, Hans-Werner Schmidt, Christoph Jonda, Martin Hüppauff, Synthesis and Application of Dimeric 1,3,5-Triazine Ethers as Hole-Blocking Materials in Electroluminescent Devices Chemistry of Materials. ,vol. 10, pp. 3620- 3625 ,(1998) , 10.1021/CM980369B
N. Serdar Sariciftci, Levent Toppare, Derya Baran, Abidin Balan, Selin Celebi, Beatriz Meana Esteban, Helmut Neugebauer, Processable Multipurpose Conjugated Polymer for Electrochromic and Photovoltaic Applications Chemistry of Materials. ,vol. 22, pp. 2978- 2987 ,(2010) , 10.1021/CM100372T
Xuebin Huang, Chunli Zhu, Shiming Zhang, Weiwei Li, Yunlong Guo, Xiaowei Zhan, Yunqi Liu, Zhishan Bo, Porphyrin−Dithienothiophene π-Conjugated Copolymers: Synthesis and Their Applications in Field-Effect Transistors and Solar Cells Macromolecules. ,vol. 41, pp. 6895- 6902 ,(2008) , 10.1021/MA801407U
Taku Hasobe, Prashant V. Kamat, Vincent Troiani, Nathalie Solladié, Tae Kyu Ahn, Seong Keun Kim, Dongho Kim, Anusorn Kongkanand, Susumu Kuwabata, Shunichi Fukuzumi, Enhancement of light-energy conversion efficiency by multi-porphyrin arrays of porphyrin-peptide oligomers with fullerene clusters. Journal of Physical Chemistry B. ,vol. 109, pp. 19- 23 ,(2005) , 10.1021/JP045246V
Marilyn M. Olmstead, David A. Costa, Kalyani Maitra, Bruce C. Noll, Shane L. Phillips, Pamela M. Van Calcar, Alan L. Balch, Interaction of Curved and Flat Molecular Surfaces. The Structures of Crystalline Compounds Composed of Fullerene (C60, C60O, C70, and C120O) and Metal Octaethylporphyrin Units Journal of the American Chemical Society. ,vol. 121, pp. 7090- 7097 ,(1999) , 10.1021/JA990618C
Pavel A. Troshin, Harald Hoppe, Joachim Renz, Martin Egginger, Julia Yu. Mayorova, Andrey E. Goryachev, Alexander S. Peregudov, Rimma N. Lyubovskaya, Gerhard Gobsch, N. Serdar Sariciftci, Vladimir F. Razumov, Material Solubility-Photovoltaic Performance Relationship in the Design of Novel Fullerene Derivatives for Bulk Heterojunction Solar Cells Advanced Functional Materials. ,vol. 19, pp. 779- 788 ,(2009) , 10.1002/ADFM.200801189
Takakazu Yamamoto, Shoutaro Watanabe, Hiroki Fukumoto, Masaru Sato, Tsuyoshi Tanaka, New Heteroaromatic Polymers Consisting of Alkyl- and Amino-1,3,5-triazine Units. Their Basic Optical Properties and n-Type Time-of-Flight Drift Mobility Macromolecular Rapid Communications. ,vol. 27, pp. 317- 321 ,(2006) , 10.1002/MARC.200500773