Guest Transport in a Nonporous Organic Solid via Dynamic van der Waals Cooperativity

作者: J. L. Atwood , L. J. Barbour , A. Jerga , B. L. Schottel

DOI: 10.1126/SCIENCE.1077591

关键词:

摘要: A well-known organic host compound undergoes single-crystal–to–single-crystal phase transitions upon guest uptake and release. Despite a lack of porosity of the material, guest transport through the solid occurs readily until a thermodynamically stable structure is achieved. In order to actively facilitate this dynamic process, the host molecules undergo significant positional and/or orientational rearrangement. This transformation of the host lattice is triggered by weak van der Waals interactions between the molecular components …

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