Magnetic [n x n] (n = 2-5) grids by directed self-assembly.

作者: Louise N. Dawe , Konstantin V. Shuvaev , Laurence K. Thompson

DOI: 10.1021/IC801078H

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摘要: Polytopic hydrazone-based ligands are discussed in the context of design attributes ligand and power self-assembly as a methodology for synthesis polymetallic systems with specific predetermined organization metal centers closely spaced bridged arrangement. Magnetic exchange coupling occurs result close proximity ions. Homometallic, heterometallic, mixed-spin-state [n x n] (n = 2-5) square grids highlighted terms their structural magnetic properties. Antiferromagnetic, ferromagnetic, ferrimagnetic examples described.

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