The Interactions and Reactions of Alkenes on Single-Crystal Surfaces of Platinum and a Comparison of Some Reactions in Homogeneous and Heterogeneous Catalysis
作者： Terence A. Clarke , Ian D. Gay , Ronald Mason
DOI: 10.1007/978-1-4615-8759-0_5
关键词:
摘要: A summary is given of our knowledge the structures and reactions organic ligands bonded to low valent metals in coordination complexes. Oxidative-addition surface metal atoms carbon-hydrogen bonds chemisorbed alkenes are shown have analogies with homogeneous systems; dissociation on nickel platinum surfaces, which demonstrated by photoelectron spectroscopy, follows metallation a bond intermolecular elimination H2 or, case halo-alkenes, HX. The stoichiometric depend substrate geometry as evidenced comparative study sorption clean Pt(100) Pt(111) surfaces.
springer.com
sci-hub.st 参考文章(31)
Melvyn R. Churchill, Ronald Mason, The Structural Chemistry of Organo-Transition Metal Complexes: Some Recent Developments Scopus. ,vol. 5, pp. 93- 135 ,(1967) , 10.1016/S0065-3055(08)60090-8
J. E. Demuth, D. E. Eastman, Photoemission Observations of π-d Bonding and Surface Reactions of Adsorbed Hydrocarbons on Ni(111) Physical Review Letters. ,vol. 32, pp. 1123- 1127 ,(1974) , 10.1103/PHYSREVLETT.32.1123
Terence A. Clarke, Ian D. Gay, Bryan Law, Ronald Mason, Chemisorption of carbon monoxide on the platinum(100) surface: A definition of electronic states by photoelectron spectroscopy Chemical Physics Letters. ,vol. 31, pp. 29- 32 ,(1975) , 10.1016/0009-2614(75)80050-9
Y Baer, P F Hedén, J Hedman, M Klasson, C Nordling, K Siegbahn, Band Structure of Transition Metals Studied by ESCA Physica Scripta. ,vol. 1, pp. 55- 65 ,(1970) , 10.1088/0031-8949/1/1/010
A. D. Walsh, 466. The electronic orbitals, shapes, and spectra of polyatomic molecules. Part I. AH2 molecules Journal of the Chemical Society (Resumed). pp. 2260- 2266 ,(1953) , 10.1039/JR9530002260
James P. Collman, Patterns of organometallic reactions related to homogeneous catalysis Accounts of Chemical Research. ,vol. 1, pp. 136- 143 ,(1968) , 10.1021/AR50005A002
R. Mason, D. M. P. Mingos, G. Rucci, J. A. Connor, Electron emission spectroscopic studies of olefin and other complexes of d 8 and d 10 metal ions Journal of the Chemical Society, Dalton Transactions. pp. 1729- 1731 ,(1972) , 10.1039/DT9720001729
S. Kowalczyk, L. Ley, R. Pollak, D.A. Shirley, High-resolution XPS spectra of Ir, Pt and Au valence bands Physics Letters A. ,vol. 41, pp. 455- 456 ,(1972) , 10.1016/0375-9601(72)90402-1
J. Chatt, L. A. Duncanson, 586. Olefin co-ordination compounds. Part III. Infra-red spectra and structure: attempted preparation of acetylene complexes Journal of the Chemical Society (Resumed). pp. 2939- 2947 ,(1953) , 10.1039/JR9530002939
R. MASON, Activation of Small Molecules by Transition Metal Ions and their Complexes Nature. ,vol. 217, pp. 543- 545 ,(1968) , 10.1038/217543A0