SIMS and XPS studies of polyurethane surfaces 2. Polyurethanes with fluorinated chain extenders
作者： D. Briggs , S. C. Yoon , B. D. Ratner , M. J. Hearn
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摘要: A series of fluorine-containing segmented poly(ether urethanes) and urethane ureas), previously characterized by angular dependent x-ray photoelectron spectroscopy (XPS) have been re-examined using static secondary ion mass spectrometry (SIMS). Comparison the data from two techniques has shown that intensity signals which characterize hard soft segments can be used quantitatively for direct analyis molecular composition at surface. Moreover, SIMS sampling depth conditions to ∼ 10 A, significantly less than XPS under normal conditions, similar high glancing take-off angle (with respect surface normal).
sci-hub.se 参考文章(18)
D. T. Clark, H. R. Thomas, Application of ESCA to polymer chemistry. XVI. Electron mean free paths as a function of kinetic energy in polymeric films determined by means of ESCA Journal of Polymer Science Part A. ,vol. 15, pp. 2843- 2867 ,(1977) , 10.1002/POL.1977.170151204
K. Kataoka, T. Okano, Y. Sakurai, T. Nishimura, S. Inoue, T. Watanabe, A. Maruyama, T. Tsuruta, Differential retention of lymphocyte subpopulations (B and T cells) on the microphase separated surface of polystyrene/polyamine graft copolymers European Polymer Journal. ,vol. 19, pp. 979- 984 ,(1983) , 10.1016/0014-3057(83)90060-5
D. Mark Hoffman, Connie M. Walkup, Ing L. Chiu, Improving adhesion between a segmented poly(ether-urethane) and a fluorocarbon copolymer coating Industrial & Engineering Chemistry Product Research and Development. ,vol. 23, pp. 572- 581 ,(1984) , 10.1021/I300016A012
D. Briggs, Analysis of polymer surfaces by SIMS: 7. Homopolymer and copolymer nylons Journal of Mass Spectrometry. ,vol. 22, pp. 91- 97 ,(1987) , 10.1002/OMS.1210220208
D. Briggs, A. B. Wootton, Analysis of polymer surfaces by SIMS 1. An investigation of practical problems Surface and Interface Analysis. ,vol. 4, pp. 109- 115 ,(1982) , 10.1002/SIA.740040306
R. F. Roberts, D. L. Allara, C. A. Pryde, D. N. E. Buchanan, N. D. Hobbins, Mean free path for inelastic scattering of 1.2 kev electrons in thin poly(methylmethacrylate) films Surface and Interface Analysis. ,vol. 2, pp. 5- 10 ,(1980) , 10.1002/SIA.740020103
C. S. Paik Sung, C. B. Hu, ESCA studies of surface chemical composition of segmented polyurethanes. Journal of Biomedical Materials Research. ,vol. 13, pp. 161- 171 ,(1979) , 10.1002/JBM.820130202
D Briggs, MJ Hearn, Interaction of ion beams with polymers, with particular reference to SIMS Vacuum. ,vol. 36, pp. 1005- 1010 ,(1986) , 10.1016/0042-207X(86)90156-9
Sung Chul Yoon, Buddy D. Ratner, Surface structure of segmented poly(ether urethanes) and poly(ether urethane ureas) with various perfluoro chain extenders. An x-ray photoelectron spectroscopic investigation Macromolecules. ,vol. 19, pp. 1068- 1079 ,(1986) , 10.1021/MA00158A023
Michael D. Lelah, Linda K. Lambrecht, Brian R. Young, Stuart L. Cooper, Physicochemical characterization and in vivo blood tolerability of cast and extruded Biomer. Journal of Biomedical Materials Research. ,vol. 17, pp. 1- 22 ,(1983) , 10.1002/JBM.820170102