Hydrogen bonding and phase equilibrium
作者： Pierre L. Huyskens , Katarine Seghers
DOI: 10.1016/0022-2860(94)87022-5
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摘要: Abstract The thermodynamics of the mobile order H-bonding in liquids considers not various H-bonded or non-H-bonded entities present solution, but fraction time (1 − γ) during which an OH proton follows electron-donor site another molecule its walk through liquid. influence H-bonds on free energy system is given by G h = n RT ln γ. ruled concentration sites and equilibrium constants may differ from those Guldberg Waage. Quantitative expressions are derived for effect solvent—solvent solute—solvent solubility crystalline substances with carbonyl ether groups. At 25°C predictions agree within 10% experimental values.
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P.L. Huyskens, M.C. Haulait-Pirson, A new expression for the combinatorial entropy of mixing in liquid mixtures Journal of Molecular Liquids. ,vol. 31, pp. 135- 151 ,(1985) , 10.1016/0167-7322(85)80030-1
P. L. Huyskens, M. C. Haulait-Pirson, G. G. Siegel, F. Kapuku, Gibbs energy of some binary systems containing hydrogen bonds The Journal of Physical Chemistry. ,vol. 92, pp. 6841- 6847 ,(1988) , 10.1021/J100334A067
P. Huyskens, Molecular structure of liquid alcohols Journal of Molecular Structure. ,vol. 100, pp. 403- 414 ,(1983) , 10.1016/0022-2860(83)90104-7
Pierre L. Huyskens, Deviations of H-bonded aggregates in liquids from the Guldberg and Waage equilibrium expression Journal of Molecular Structure. ,vol. 297, pp. 141- 147 ,(1993) , 10.1016/0022-2860(93)80169-V
Marie Claire Haulait-Pirson, Greta Huys, Eddy Vanstraelen, New predictive equation for the solubility of solid n-alkanes in organic solvents Industrial & Engineering Chemistry Research. ,vol. 26, pp. 447- 452 ,(1987) , 10.1021/IE00063A008
P. A. Small, Some factors affecting the solubility of polymers Journal of Chemical Technology & Biotechnology. ,vol. 3, pp. 71- 80 ,(2007) , 10.1002/JCTB.5010030205
Werner A. P. Luck, Modellbetrachtung von Flüssigkeiten mit Wasserstoffbrücken Angewandte Chemie. ,vol. 92, pp. 29- 42 ,(1980) , 10.1002/ANGE.19800920107
Paul Ruelle, Catherine Rey‐Mermet, Michel Buchmann, Hô Nam‐Tran, Ulrich W. Kesselring, P. L. Huyskens, A new predictive equation for the solubility of drugs based on the thermodynamics of mobile disorder. Pharmaceutical Research. ,vol. 8, pp. 840- 850 ,(1991) , 10.1023/A:1015891126287