6.16 Functional Group Transformation via Allyl Rearrangement
作者： Z. Gu , A. Zakarian
DOI: 10.1016/B978-0-08-097742-3.00624-8
关键词:
摘要: This chapter describes recent developments in the versatile and multifaceted chemistry of allylic transposition reactions, concentrating on contributions reported past decade. In beginning chapter, authors describe a variety mechanistic pathways by which substitution reactions occur, including nucleophilic, electrophilic, radical, organometallic, concerted pericyclic processes. discussion is followed examples representative with preference for products based identity leaving incoming atoms newly installed group. The are broadly grouped into heteroatom transpositions heteroatom-to-carbon transpositions. As evident from presented material, astonishingly rich will continue to be foundation development powerful innovative chemical methodology.
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