Hydroxyapatite thin film coatings on nanotube-formed Ti–35Nb–10Zr alloys after femtosecond laser texturing

作者: Yong-Hoon Jeong , Han-Cheol Choe , William A. Brantley , Ik-Bu Sohn

DOI: 10.1016/J.SURFCOAT.2012.11.066

关键词:

摘要: Abstract To achieve excellent biocompatibility of metal-based implants, hydroxyapatite thin film coatings on nanotube-formed Ti–35Nb–10Zr alloys after femtosecond laser texturing have been investigated. Three groups samples were prepared: (1) microtextured surfaces using (FS) laser, (2) nanotube formed by anodization, and (3) vapor-deposited a physical electron beam method the ternary alloy. The surface morphology was examined x-ray diffractometry, field-emission scanning microscopy, energy-dispersive spectroscopy. investigate ion release, potentiodynamic polarization testing carried out in 0.9%NaCl solution, wettability tests MG 63 osteoblast-like cell culture studies performed three to evaluate contact angle growth morphology, respectively. exhibited equiaxed β phase structure. FS laser-treated showed circular traces with diameters 28 ± 1.5 μm hole separations 50 μm, nanotubes had 180 ± 15 nm compositions consistent TiO 2 , Nb O 5 ZrO . structure anatase, rutile β-titanium diffraction peaks, whereas HA-coated hydroxyapatite, anatase peaks. HA displayed desired role decreasing metal release lower current density value, wider passive regions compared other surfaces. lowest From FE-SEM observations, attachment spreading 63 cells significantly higher tendency for covered coating nanotubes.

参考文章(33)
N. Mirhosseini, P.L. Crouse, M.J.J. Schmidth, L. Li, D. Garrod, Laser surface micro-texturing of Ti-6Al-4V substrates for improved cell integration Applied Surface Science. ,vol. 253, pp. 7738- 7743 ,(2007) , 10.1016/J.APSUSC.2007.02.168
XJ Feng, JM Macak, SP Albu, P Schmuki, None, Electrochemical formation of self-organized anodic nanotube coating on Ti-28Zr-8Nb biomedical alloy surface. Acta Biomaterialia. ,vol. 4, pp. 318- 323 ,(2008) , 10.1016/J.ACTBIO.2007.08.005
Yong-Hoon JEONG, Won-Gi KIM, Geun-Hyeong PARK, Han-Cheol CHOE, Yeong-Mu KO, Surface characteristics of HA coated Ti-Hf binary alloys after nanotube formation Transactions of Nonferrous Metals Society of China. ,vol. 19, pp. 852- 856 ,(2009) , 10.1016/S1003-6326(08)60363-5
Yong-Hoon Jeong, Han-Cheol Choe, William A. Brantley, Nanostructured thin film formation on femtosecond laser-textured Ti–35Nb–xZr alloy for biomedical applications Thin Solid Films. ,vol. 519, pp. 4668- 4675 ,(2011) , 10.1016/J.TSF.2011.01.014
Yong-Hoon Jeong, Han-Cheol Choe, Sang-Won Eun, Hydroxyapatite coating on the Ti–35Nb–xZr alloy by electron beam-physical vapor deposition Thin Solid Films. ,vol. 519, pp. 7050- 7056 ,(2011) , 10.1016/J.TSF.2011.04.086
Yong-Hoon Jeong, Kang Lee, Han-Cheol Choe, Yeong-Mu Ko, William A. Brantley, Nanotube formation and morphology change of Ti alloys containing Hf for dental materials use Thin Solid Films. ,vol. 517, pp. 5365- 5369 ,(2009) , 10.1016/J.TSF.2009.03.167
Tatsuo Tsunoda, Masakazu Mukaida, Yoji Imai, Thermoelectric properties of Ru- or Ge-doped β-FeSi2 films prepared by electron beam deposition Thin Solid Films. ,vol. 381, pp. 296- 302 ,(2001) , 10.1016/S0040-6090(00)01759-4
J. Siejka, C. Ortega, An O18 Study of Field‐Assisted Pore Formation in Compact Anodic Oxide Films on Aluminum Journal of The Electrochemical Society. ,vol. 124, pp. 883- 891 ,(1977) , 10.1149/1.2133446
Frank Schwarz, Marco Wieland, Zvi Schwartz, Ge Zhao, Frank Rupp, Jürgen Geis-Gerstorfer, Andreas Schedle, Nina Broggini, Michael M. Bornstein, Daniel Buser, Stephen J. Ferguson, Jürgen Becker, Barbara D. Boyan, David L. Cochran, Potential of chemically modified hydrophilic surface characteristics to support tissue integration of titanium dental implants. Journal of Biomedical Materials Research Part B. ,vol. 88, pp. 544- 557 ,(2009) , 10.1002/JBM.B.31233