Formation of intermetallic phases in Al-coated hot-stamped 22MnB5 sheets in terms of coating thickness and Si content

作者: M. Windmann , A. Röttger , W. Theisen

DOI: 10.1016/J.SURFCOAT.2014.02.056

关键词:

摘要: Abstract AlSiFe coatings with differing thicknesses and Si contents were applied to steel sheets by hot dipping. The austenitized at TAUS = 920 °C for different dwell times then quenched in water. Phase formation as a function of coating thickness content the substrate/coating interface was investigated ex-situ phase analysis synchrotron radiation electron backscatter diffraction (EBSD). X-ray (XRD) EBSD investigations confirmed AlFe-rich intermetallics steel/coating result strong diffusion elements Al Fe. Within first minute, Fe into partially melted Al-base promotes type Al8Fe2Si, Al13Fe4, Al5Fe2. After has transformed completely Al–Fe intermetallics, substrate becomes more pronounced, thus reducing promoting phases Al2Fe AlFe an Al-rich bcc layer substrate. transformation kinetics resulting Al-, Fe-rich are influenced chemical composition coating. On one hand, faster saturation is promoted shorter path therefore thinner thickness. Otherwise, influences diffusivity Si-richer which act nuclei Fe-richer intermetallics.

参考文章(17)
U. Reisgen, L. Stein, M. Steiners, A. Göttmann, Lichtbogenfügen umformbarer Stahl‐Aluminium‐Mischverbindungen Materialwissenschaft Und Werkstofftechnik. ,vol. 41, pp. 951- 960 ,(2010) , 10.1002/MAWE.201000690
U Köster, W Liu, H Liebertz, M Michel, Mechanical properties of quasicrystalline and crystalline phases in AlCuFe alloys Journal of Non-crystalline Solids. ,vol. 153, pp. 446- 452 ,(1993) , 10.1016/0022-3093(93)90393-C
A. Mein, G. Fourlaris, D. Crowther, P.J. Evans, The influence of aluminium on the ferrite formation and microstructural development in hot rolled dual-phase steel Materials Characterization. ,vol. 64, pp. 69- 78 ,(2012) , 10.1016/J.MATCHAR.2011.11.016
P. Peyre, G. Sierra, F. Deschaux-Beaume, D. Stuart, G. Fras, Generation of aluminium–steel joints with laser-induced reactive wetting Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 444, pp. 327- 338 ,(2007) , 10.1016/J.MSEA.2006.09.111
T. Maitra, S.P. Gupta, Intermetallic compound formation in Fe–Al–Si ternary system: Part II Materials Characterization. ,vol. 49, pp. 293- 311 ,(2002) , 10.1016/S1044-5803(03)00005-6
M. Windmann, A. Röttger, W. Theisen, Phase formation at the interface between a boron alloyed steel substrate and an Al-rich coating Surface & Coatings Technology. ,vol. 226, pp. 130- 139 ,(2013) , 10.1016/J.SURFCOAT.2013.03.045
H. Springer, A. Kostka, E.J. Payton, D. Raabe, A. Kaysser-Pyzalla, G. Eggeler, On the formation and growth of intermetallic phases during interdiffusion between low-carbon steel and aluminum alloys Acta Materialia. ,vol. 59, pp. 1586- 1600 ,(2011) , 10.1016/J.ACTAMAT.2010.11.023
Shigeaki Kobayashi, Takao Yakou, Control of intermetallic compound layers at interface between steel and aluminum by diffusion-treatment Materials Science and Engineering A-structural Materials Properties Microstructure and Processing. ,vol. 338, pp. 44- 53 ,(2002) , 10.1016/S0921-5093(02)00053-9
G. Eggeler, W. Auer, H. Kaesche, On the influence of silicon on the growth of the alloy layer during hot dip aluminizing Journal of Materials Science. ,vol. 21, pp. 3348- 3350 ,(1986) , 10.1007/BF00553379
Hoon Huh, Seok-Bong Kim, Jung-Han Song, Ji-Ho Lim, Dynamic tensile characteristics of TRIP-type and DP-type steel sheets for an auto-body International Journal of Mechanical Sciences. ,vol. 50, pp. 918- 931 ,(2008) , 10.1016/J.IJMECSCI.2007.09.004