RISM analysis of tetrachloride liquids

作者: E. Enciso , C. Martin , M.B. Deraman , J.C. Dore

DOI: 10.1080/00268978700100351

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摘要: Neutron diffraction measurements have been made for CCl4/SnCl4 liquid mixtures. The tetrahedral molecules different sizes but the scattering from central atom is identical. results indicate a systematic effect of anisotropy on magnitude first two peaks and are in good agreement with theoretical predictions obtained by solving RISM integral equation using hard core model which effective diameter chlorine atoms was evaluated Barker-Henderson criterion. We also discuss main features interlocking arrangement these as shown various pair correlation functions possibility two-fluid describing intermolecular structure factor

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