Self-Assembly of Bottlebrush Block Copolymers in Selective Solvent: Micellar Structures.
作者： Ekaterina B. Zhulina , Oleg V. Borisov , Inna O. Lebedeva
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摘要: Block copolymers comprising chemically different bottlebrush blocks can self-assemble in selective solvents giving rise to micellar-like solution nanostructures. The self-consistent field theoretical approach is used for predicting relation between architectural parameters of both bottlebrush blocks (polymerization degrees of the main and side chains, density of grafting of the side chains to the backbone) and structural properties of micelles as well as critical micelle concentration (CMC). As predicted by the theory, replacement of linear blocks …
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