Application of ion chemistry and the SIFT technique to the quantitative analysis of trace gases in air and on breath

作者: David Smith , Patrik Španěl

DOI: 10.1080/01442359609353183

关键词:

摘要: Abstract Our major objective in this paper is to describe a new method we have developed for the analysis of trace gases at partial pressures down ppb level atmospheric air, with special emphasis on detection and quantification human breath. It involves use our selected ion flow tube (Sift) technique which previously used extensively study gas phase ionic reactions occurring ionized media such as terrestrial atmosphere interstellar clouds. Before discussing analytical results very recent Sift flowing afterglow (FA) studies H3O+ OH− ions, their hydrates H3O+(H2O)1,2,3 (H2O)1,2, NO+ O2 +, several hydrocarbons oxygen-bearing organic molecules, that are relevant studies. Then follows detailed discussion application analysis, after presen...

参考文章(56)
David Smith, Nigel G. Adams, Elementary plasma reactions of environmental interest Springer, Berlin, Heidelberg. pp. 1- 43 ,(1980) , 10.1007/3540098259_4
Ashley D. Williamson, J. L. Beauchamp, Ion-molecule reactions of nitric oxide(1+) ion with organic molecules by ion cyclotron resonance spectroscopy Journal of the American Chemical Society. ,vol. 97, pp. 5714- 5718 ,(1975) , 10.1021/JA00853A013
Michael T. Bowers, Gas phase ion chemistry Elsevier Science. ,(1979)
James M. Farrar, William Hundley Saunders, Techniques for the study of ion-molecule reactions Wiley. ,(1988)
D. Smith, N.G. Adams, The Selected Ion Flow Tube (Sift): Studies of Ion-Neutral Reactions Advances in atomic and molecular physics. ,vol. 24, pp. 1- 49 ,(1988) , 10.1016/S0065-2199(08)60229-8
Stuart K. Searles, L. Wayne Sieck, High Pressure Photoionization Mass Spectrometry. III. Reactions of NO+(X 1Σ+) with C3–C7Hydrocarbons at Thermal Kinetic Energies The Journal of Chemical Physics. ,vol. 53, pp. 794- 798 ,(1970) , 10.1063/1.1674061
David Smith, Patrik Ŝpanêl, Studies of Electron Attachment at Thermal Energies Using the Flowing Afterglow–Langmuir Probe Technique Advances in Atomic Molecular and Optical Physics. ,vol. 32, pp. 307- 343 ,(1994) , 10.1016/S1049-250X(08)60022-1
E.E. Ferguson, F.C. Fehsenfeld, A.L. Schmeltekopf, Flowing Afterglow Measurements of Ion-Neutral Reactions Advances in atomic and molecular physics. ,vol. 5, pp. 1- 56 ,(1969) , 10.1016/S0065-2199(08)60154-2
Bruce J. McIntosh, Nigel G. Adams, David Smith, Determination of the proton affinities of H2O and CS2 relative to C2H4 Chemical Physics Letters. ,vol. 148, pp. 142- 148 ,(1988) , 10.1016/0009-2614(88)80290-2
Gervase I. Mackay, Scott D. Tanner, Alan C. Hopkinson, Diethard K. Bohme, Gas-phase proton-transfer reactions of the hydronium ion at 298 K Canadian Journal of Chemistry. ,vol. 57, pp. 1518- 1523 ,(1979) , 10.1139/V79-248