Diastereoselective π-facially controlled nucleophilic additions of chiral vinylorganometallics to chiral β,γ-unsaturated ketones. 2. A practical method for stereocontrolled elaboration of the decahydro--indacene subunit of ikarugamycin
作者： Leo A Paquette , Jeffrey L Romine , Ho-Shen Lin
DOI: 10.1016/S0040-4039(00)95641-7
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摘要: Abstract 7,7-Dimethoxy-5-norbornen-2-one has been converted in 7 steps to tricyclic enone 10 , which comprises a principal subunit of the ikarugamycin structure.
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