Phase equilibria in LaBr3-TlBr pseudobinary system. Thermodynamic assessment of LaBr3-MBr (M = Li, Na, K, Rb, Cs, Tl) pseudobinary systems
作者： B. Salamon , J. Kapała , L. Rycerz , I. Szczygieł
DOI: 10.1016/J.CALPHAD.2019.03.006
关键词:
摘要: Abstract The phase equilibria in the lanthanum(III) bromide-thallium bromide pseudobinary system was established by means of differential scanning calorimetry (DSC). DSC investigations were performed on samples with different compositions whole mole fraction x(LaBr3) range. This includes one intermediate compound Tl2LaBr5. It melts congruently at 829 K. TlBr-Tl2LaBr5 and Tl2LaBr5-LaBr3 eutectics, corresponding to LaBr3 x = 0.088 (T = 687 K) x = 0.491 (T = 788 K) respectively, found from Tammann's plot. LaBr3-TlBr also optimized CALPHAD method using available experimental data. Experimental calculated data concerning compared for LaBr3-MBr (M = Li-Cs) systems, which have been method. thermodynamic properties liquid systems modelled Associated Solution Model {3 M+ + LaBr63−} (M = Li-Cs, Tl) associate. dependencies mixing enthalpy entropy estimated all investigated systems. formation Gibbs energy temperature range existence compounds discussed. optimization indicates that participation associate (M = K⋯Cs, increases increase ionic radius monovalent metal.
sci-hub.se 参考文章(36)
M. Tisza, Physical metallurgy for engineers ASM International. ,(2001)
H J Seifert, Ternary chlorides of the trivalent late lanthanides Journal of Thermal Analysis and Calorimetry. ,vol. 83, pp. 479- 505 ,(2006) , 10.1007/S10973-005-7132-7
L. Rycerz, M. Gaune-Escard, Enthalpy of Phase Transitions and Heat Capacity of Stoichiometric Compounds in LaBr3-MBr Systems (M=K, Rb, Cs) Journal of Thermal Analysis and Calorimetry. ,vol. 56, pp. 355- 363 ,(1999) , 10.1023/A:1010102802661
Julien Andres, Anne-Sophie Chauvin, Lanthanides: Luminescence Applications Encyclopedia of Inorganic and Bioinorganic Chemistry. ,(2012) , 10.1002/9781119951438.EIBC2067
C. E. Wicks, F. E. Block, Thermodynamic Properties of 65 Elements: Their Oxides, Halides, Carbides and Nitrides United States. Government Printing Office.. ,(1963)
Zane C. Gernhart, Anuja Bhalkikar, John J. Burke, Kate O. Sonnenfeld, Chris M. Marin, Richard Zbasnik, Chin Li Cheung, One-pot conversion of cellobiose to mannose using a hybrid phosphotungstic acid–cerium oxide catalyst RSC Advances. ,vol. 5, pp. 28478- 28486 ,(2015) , 10.1039/C5RA02645H
Arthur D. Pelton, Milton Blander, Thermodynamic analysis of ordered liquid solutions by a modified quasichemical approach—Application to silicate slags Metallurgical and Materials Transactions B-process Metallurgy and Materials Processing Science. ,vol. 17, pp. 805- 815 ,(1986) , 10.1007/BF02657144
Jan Kapała, Beata Salamon, Thermodynamic assessment of TbCl3–MCl (M=Na, K, Rb, Cs) binary systems Calphad-computer Coupling of Phase Diagrams and Thermochemistry. ,vol. 43, pp. 139- 142 ,(2013) , 10.1016/J.CALPHAD.2013.06.001
G.D. Zissi, A. Chrissanthopoulos, G.N. Papatheodorou, Vibrational modes and structure of the LaCl3CsCl melts Vibrational Spectroscopy. ,vol. 40, pp. 110- 117 ,(2006) , 10.1016/J.VIBSPEC.2005.07.005
H. L. Lukas, S. G. Fries, Demonstration of the use of “BINGSS” with the Mg-Zn system as example Journal of Phase Equilibria. ,vol. 13, pp. 532- 542 ,(1992) , 10.1007/BF02665766