IM-5: A Highly Thermal and Hydrothermal Shape-Selective Cracking Zeolite

作者: Avelino Corma , Joaquı́n Martı́nez-Triguero , Susana Valencia , Eric Benazzi , Sylvie Lacombe

DOI: 10.1006/JCAT.2001.3469

关键词:

摘要: Abstract Zeolite IM-5 shows a higher thermal and hydrothermal stability than that of ZSM-5, the rate dealumination being slower, as shown by 29 Si 27 Al magic-angle spinning nuclear magnetic resonance. This is responsible for larger acidity after calcination steaming. When cracking paraffin, cycloparaffin, olefin model compounds, this zeolite gives activity ZSM-5 with similar shape selectivity. used fluid catalytic additive, improved its increasing olefin-to-paraffin ratios in products, having special impact on production propylene.

参考文章(11)
H.S. Cerqueria, M.G.F. Rodrigues, P. Magnoux, D. Martin, M. Guisnet, Transformation of methylcyclohexane over fresh HFAU and HMFI zeolites: reaction scheme and kinetic modelling Studies in Surface Science and Catalysis. ,vol. 130, pp. 2477- 2482 ,(2000) , 10.1016/S0167-2991(00)80841-1
M. D. Shannon, J. L. Casci, P. A. Cox, S. J. Andrews, Structure of the two-dimensional medium-pore high-silica zeolite NU-87 Nature. ,vol. 353, pp. 417- 420 ,(1991) , 10.1038/353417A0
Avelino Corma, F. Mocholi, V. Orchilles, Gerald S. Koermer, Rostam J. Madon, Methylcyclohexane and methylcyclohexene cracking over zeolite Y catalysts Applied Catalysis. ,vol. 67, pp. 307- 324 ,(1990) , 10.1016/S0166-9834(00)84453-X
A. Corma, A. Chica, J.M. Guil, F.J. Llopis, G. Mabilon, J.A. Perdigón-Melón, S. Valencia, Determination of the pore topology of zeolite IM-5 by means of catalytic test reactions and hydrocarbon adsorption measurements Journal of Catalysis. ,vol. 189, pp. 382- 394 ,(2000) , 10.1006/JCAT.1999.2718
M. E. Leonowicz, J. A. Lawton, S. L. Lawton, M. K. Rubin, MCM-22: A Molecular Sieve with Two Independent Multidimensional Channel Systems Science. ,vol. 264, pp. 1910- 1913 ,(1994) , 10.1126/SCIENCE.264.5167.1910
A. Corma, J. Martínez-Triguero, Kinetics of gasoil cracking and catalyst decay on SAPO-37 and USY molecular sieves Applied Catalysis A-general. ,vol. 118, pp. 153- 162 ,(1994) , 10.1016/0926-860X(94)80310-2
Avelino Corma, Joaquı́n Martı́nez-Triguero, The Use of MCM-22 as a Cracking Zeolitic Additive for FCC Journal of Catalysis. ,vol. 165, pp. 102- 120 ,(1997) , 10.1006/JCAT.1997.1474