Synthesis of polymer precursors of electroactive materials by SET-LRP

摘要: The synthesis of electroactive polymer precursors by single electron transfer-living radical polymerisation (SET-LRP) is demonstrated here. Standard SET-LRP conditions are employed for the controlled 2,2,6,6-tetramethylpiperidin-4-yl methacrylate (TMPM). behaviour under these kinetic experiments. Moreover, functional block copolymers investigated with 3-azidopropyl (AzPMA). TMPM containing (co)polymers oxidised to produce poly(TEMPO methacrylate) (PTMA). redox PTMA was furthermore evidenced cyclic voltamperometry. These polymers promising in frame organic batteries.