Effect of catalyst composition on the hydrogenolysis of anisole

作者: M.K. Huuska

DOI: 10.1016/S0277-5387(00)84915-3

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摘要: Abstract The hydrogenolysis of anisole was studied in a fixed-bed reactor at 300°C and 5 MPa hydrogen pressure on pure carriers different catalysts containing Mo or Ni. Catalysts based an acidic carrier gave mainly phenol methyl-substituted phenols. On without support very little methyl substitution occurred the main products were cyclic hydrocarbons. Reaction mechanisms structure possible active sites are briefly discussed.

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