Liquid-phase catalytic hydrogenation using palladium alloy membranes

作者: T.S. Farris , J.N. Armor

DOI: 10.1016/0926-860X(93)80004-A

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摘要: Abstract The hydrogenation of several liquid alkenes was studied over Pd/Ru alloy membranes in either metal or glass membrane reactors. For cyclohexene, cyclo-octadiene, and octadecene as liquids, conversions ca. 2–5% were common contrast to the facile conversion acetylenic alcohols.

参考文章(6)
Christopher Anderson, US challenge to AZT patent. Nature. ,vol. 349, pp. 93- 93 ,(1991) , 10.1038/349093A0
Vladimir M Gryaznov, Mikhail G Slin'ko, None, Selectivity in catalysis by hydrogen-porous membranes Faraday Discussions of the Chemical Society. ,vol. 72, pp. 73- 78 ,(1981) , 10.1039/DC9817200073
J.N. Armor, Catalysis with permselective inorganic membranes Applied Catalysis. ,vol. 49, pp. 1- 25 ,(1989) , 10.1016/S0166-9834(00)81418-9
N.R. Roshan, A.P. Mishchenko, V.P. Polyakova, N.I. Parfenova, E.M. Savitsky, E.A. Voitekhova, V.M. Gryaznov, M.E. Sarylova, The effect of the surface state on the hydrogen permeability and the catalytic activity of palladium alloy membranes Journal of The Less Common Metals. ,vol. 89, pp. 423- 428 ,(1983) , 10.1016/0022-5088(83)90352-1
Qunyin Xu, Marc A. Anderson, Synthesis of porosity controlled ceramic membranes Journal of Materials Research. ,vol. 6, pp. 1073- 1081 ,(1991) , 10.1557/JMR.1991.1073
J. Shu, B. P. A. Grandjean, A. Van Neste, S. Kaliaguine, Catalytic palladium‐based membrane reactors: A review Canadian Journal of Chemical Engineering. ,vol. 69, pp. 1036- 1060 ,(1991) , 10.1002/CJCE.5450690503