Chemistry of acetylenic ethers, 67: Allenyl thioethers from alkynyl thioethers
作者： L. Brandsma , H. E. Wijers , J. F. Arens
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摘要: The isomeric allenyl thioethers, III, are produced in good yield by treating 1-ethylthio-1-alkynes, I, with an equivalent amount of sodamide liquid ammonia, followed hydrolysis the reaction mixture. The corresponding thioethers alkylated 1-position, IV, obtained, also yield, adding primary or secondary alkyl halides to product and I.
sci-hub.se 参考文章(3)
L. Brandsma, H. Wijers, J. F. Arens, Chemistry of acetylenic ethers. LXI: A simple method for the preparation of acetylenic thioethers, selenoethers and telluroethers (Preliminary publication) Recueil des Travaux Chimiques des Pays-Bas. ,vol. 81, pp. 583- 584 ,(2010) , 10.1002/RECL.19620810707
H. J. Boonstra, L. Brandsma, A. M. Wiegman, J. F. Arens, Chemistry of acetylenic ethers XXXVI. Preparation and properties of some 1-alkylthio-1-alkynes Recueil des Travaux Chimiques des Pays-Bas. ,vol. 78, pp. 252- 264 ,(2010) , 10.1002/RECL.19590780405
Thomas H. Vaughn, R. R. Vogt, J. A. Nieuwland, A Rapid Catalytic Preparation of Sodamide in Liquid Ammonia and Some of its Uses in the Preparation of Acetylenic Materials Journal of the American Chemical Society. ,vol. 56, pp. 2120- 2122 ,(1934) , 10.1021/JA01325A038