Removal of levofloxacin from aqueous solution using rice-husk and wood-chip biochars

作者: Shengze Yi , Bin Gao , Yuanyuan Sun , Jichun Wu , Xiaoqing Shi

DOI: 10.1016/J.CHEMOSPHERE.2015.12.112

关键词:

摘要: The potential for rice husk (RH) and wood chip (WC) biochars to remove levofloxacin (LEV) from aqueous solution was evaluated. physical chemical properties of the were characterized using various tools techniques. Furthermore, batch sorption experiments conducted determine ability LEV. pseudo-second order kinetic model described data better than pseudo-first Elovich equation because process involved both surface adsorption pore diffusion. For isotherms, Langmuir fitted Freundlich equation. maximum capacities LEV ranged 1.49 7.72 mg g(-1). Thermodynamic parameters obtained showed that onto WC biochar spontaneous exothermic, while its RH endothermic under tested conditions. A mixture 0.025 M phosphate buffer (80%, pH 3.0) acetonitrile (20%) effectively desorbed with a recovery rate up 80%. Findings this work indicate can be used as an alternative adsorbent emerging contaminants including solutions.

参考文章(45)
Ling Zhao, Xinde Cao, Wei Zheng, Qun Wang, Fan Yang, Endogenous minerals have influences on surface electrochemistry and ion exchange properties of biochar Chemosphere. ,vol. 136, pp. 133- 139 ,(2015) , 10.1016/J.CHEMOSPHERE.2015.04.053
Mohammad Boshir Ahmed, John L. Zhou, Huu Hao Ngo, Wenshan Guo, Adsorptive removal of antibiotics from water and wastewater: Progress and challenges. Science of The Total Environment. ,vol. 532, pp. 112- 126 ,(2015) , 10.1016/J.SCITOTENV.2015.05.130
M Hema, S Arivoli, COMPARATIVE STUDY ON THE ADSORPTION KINETICS AND THERMODYNAMICS OF DYES ONTO ACID ACTIVATED LOW COST CARBON INTERNATIONAL JOURNAL OF PHYSICAL SCIENCES. ,vol. 2, pp. 10- 17 ,(2007)
Christopher O. Cope, Damon S. Webster, David A. Sabatini, Arsenate adsorption onto iron oxide amended rice husk char. Science of The Total Environment. ,vol. 488, pp. 554- 561 ,(2014) , 10.1016/J.SCITOTENV.2013.12.120
S Mustafa, B Dilara, K Nargis, A Naeem, P Shahida, Surface properties of the mixed oxides of iron and silica Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 205, pp. 273- 282 ,(2002) , 10.1016/S0927-7757(02)00025-0
D. Harikishore Kumar Reddy, Y. Harinath, K. Seshaiah, A.V.R. Reddy, Biosorption of Pb(II) from aqueous solutions using chemically modified Moringa oleifera tree leaves. Chemical Engineering Journal. ,vol. 162, pp. 626- 634 ,(2010) , 10.1016/J.CEJ.2010.06.010
Hong Yao, Jian Lu, Jun Wu, Zeyu Lu, P. Chris Wilson, Yan Shen, Adsorption of Fluoroquinolone Antibiotics by Wastewater Sludge Biochar: Role of the Sludge Source Water Air and Soil Pollution. ,vol. 224, pp. 1370- ,(2013) , 10.1007/S11270-012-1370-7
Di Zhang, Bo Pan, Huang Zhang, Ping Ning, Baoshan Xing, Contribution of Different Sulfamethoxazole Species to Their Overall Adsorption on Functionalized Carbon Nanotubes Environmental Science & Technology. ,vol. 44, pp. 3806- 3811 ,(2010) , 10.1021/ES903851Q
Zaira Zaman Chowdhury, Md. Rakibul Hasan, Sharifah Bee Abd Hamid, Emy Marlina Samsudin, Sharifuddin Mohd. Zain, Khalisanni Khalid, Catalytic pretreatment of biochar residues derived from lignocellulosic feedstock for equilibrium studies of manganese, Mn(II) cations from aqueous solution RSC Advances. ,vol. 5, pp. 6345- 6356 ,(2015) , 10.1039/C4RA09709B
Mandu Inyang, Bin Gao, Wenchuan Ding, Pratap Pullammanappallil, Andrew R. Zimmerman, Xinde Cao, Enhanced Lead Sorption by Biochar Derived from Anaerobically Digested Sugarcane Bagasse Separation Science and Technology. ,vol. 46, pp. 1950- 1956 ,(2011) , 10.1080/01496395.2011.584604