Surface composition and morphology of poly(3-hydroxybutyrate) exposed to biodegradation
作者： M.C.S. Corrêa , M.L. Rezende , D.S. Rosa , J.A.M. Agnelli , P.A.P. Nascente
DOI: 10.1016/J.POLYMERTESTING.2008.01.007
关键词:
摘要: Injected samples of poly(3-hydroxybutyrate) (PHB) were exposed to biodegradation in simulated soil and then characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), differential calorimetry (DSC), roughness weight loss. The decomposition medium was evaluated measurements pH, humidity amounts carbon nitrogen. loss test indicated a significant decrease with time, which more intense the first 3 months biodegradation. results obtained means XPS, SEM, DSC analyses suggested possible layer-by-layer degradation process having 3-month period.
elsevier.com
sci-hub.se 参考文章(19)
Gerald Scott, Dan Gilead, Degradable polymers : principles and applications Kluwer Academic Publishers. ,(1995)
Mal-Nam Kim, Ae-Ri Lee, Jin-San Yoon, In-Joo Chin, Biodegradation of poly(3-hydroxybutyrate), Sky-Green® and Mater-Bi® by fungi isolated from soils European Polymer Journal. ,vol. 36, pp. 1677- 1685 ,(2000) , 10.1016/S0014-3057(99)00219-0
Mal-Nam Kim, Ae-Ri Lee, Kwang-Hee Lee, In-Joo Chin, Jin-San Yoon, Biodegradability of poly(3-hydroxybutyrate) blended with poly(ethylene-co-vinyl acetate) or poly(ethylene oxide) European Polymer Journal. ,vol. 35, pp. 1153- 1158 ,(1999) , 10.1016/S0014-3057(98)00089-5
C.S.K Reddy, R Ghai, Rashmi, V.C Kalia, Polyhydroxyalkanoates: an overview. Bioresource Technology. ,vol. 87, pp. 137- 146 ,(2003) , 10.1016/S0960-8524(02)00212-2
D.S Rosa, R.P Filho, Q.S.H Chui, M.R Calil, C.G.F Guedes, The biodegradation of poly-β-(hydroxybutyrate), poly-β-(hydroxybutyrate-co-β-valerate) and poly(ε-caprolactone) in compost derived from municipal solid waste European Polymer Journal. ,vol. 39, pp. 233- 237 ,(2003) , 10.1016/S0014-3057(02)00215-X
Derval dos Santos Rosa, Maria Regina Calil, Cristina das Gra�as Fassina Guedes, T�lio C�sar Rodrigues, Biodegradability of Thermally Aged PHB, PHB-V, and PCL in Soil Compostage Journal of Polymers and The Environment. ,vol. 12, pp. 239- 245 ,(2004) , 10.1007/S10924-004-8151-3
M Arcana, O Giani-Beaune, F Schu�, W Amass, A Amass, Structure and morphology of poly(β‐hydroxybutyrate) synthesized by ring‐opening polymerization of racemic (R,S)‐β‐butyrolactone with distannoxane derivatives Polymer International. ,vol. 49, pp. 1348- 1355 ,(2000) , 10.1002/1097-0126(200011)49:11<1348::AID-PI491>3.0.CO;2-H
K Sudesh, H Abe, Y Doi, Synthesis, structure and properties of polyhydroxyalkanoates: biological polyesters Progress in Polymer Science. ,vol. 25, pp. 1503- 1555 ,(2000) , 10.1016/S0079-6700(00)00035-6
Robert J. Watkinson, Philip Morgan, Physiology of aliphatic hydrocarbon-degrading microorganisms. Biodegradation. ,vol. 1, pp. 79- 92 ,(1990) , 10.1007/BF00058828
D.S Rosa, N.T Lotto, D.R Lopes, C.G.F Guedes, The use of roughness for evaluating the biodegradation of poly-β-(hydroxybutyrate) and poly-β-(hydroxybutyrate-co-β- valerate) Polymer Testing. ,vol. 23, pp. 3- 8 ,(2004) , 10.1016/S0142-9418(03)00042-4