Mechanism of Charge/Discharge of Poly(vinylphenothiazine)-Based Li–Organic Batteries

摘要: Organic electrode materials are among the promising next generation compounds for battery energy storage as a greener and cheaper alternative to transition-metal-based electrodes. A prominent class them redox polymers, which can reversibly store be capable of fast processes. Nevertheless, drawbacks their often low specific lifetime. main challenge is solubility in electrolytes, detrimental cell performance. Herein, we discuss properties polyvinyl-based polymer with methylphenothiazine side group (PVMPT) organic-solvent-based electrolytes generate new insights into mechanism redeposition process dissolved active material. We addressed mechanistic studies this “polymer–electrolyte cross-talk” microscopic spectroscopic methods. These findings important molecular design organic materials, since redeposited showed improved cy...