Correction for a possible reversible adsorption over an “inert” material

摘要: All TAP micro-reactor configurations contain inert particles which are used so that the catalyst zone can be maintained under isothermal conditions. Even on “inert” adsorption will occur to some degree; however, extent this occurs has a critical influence analysis of data. In many cases assumption there is no interaction between probe molecules and required as reversible over material problematic when model solved. Moreover, pulse response experiments designed conducted within Knudsen diffusion regime, central data characterization diffusional transport reagent through micro-reactor, achieved via “diffusion only” an one packing. Therefore, if any processes occurring in addition material, such adsorption, it important factor these into analysis. If additional not included, entire would questionable. The current work discloses development function accounts for accurately determined. This newly developed method been exemplified using selective reduction oxygen hydrogen rich ethylene feed silver catalysts case study.