Separation of cobalt and nickel using a thermomorphic ionic-liquid-based aqueous biphasic system
作者： Bieke Onghena , Tomas Opsomer , Koen Binnemans
DOI: 10.1039/C5CC06595J
关键词:
摘要: A [P44414][Cl]–NaCl–H2O ionic liquid-based aqueous biphasic system shows promising results for the separation of cobalt(II) and nickel(II) by homogeneous liquid–liquid extraction. The extracting phase consists a hydrophilic liquid that is salted-out sodium chloride, indicating there no need using hydrophobic liquids.
rsc.org
kuleuven.be
sci-hub.se 参考文章(31)
David Dupont, Daphne Depuydt, Koen Binnemans, Overview of the effect of salts on biphasic ionic liquid/water solvent extraction systems: anion exchange, mutual solubility, and thermomorphic properties. Journal of Physical Chemistry B. ,vol. 119, pp. 6747- 6757 ,(2015) , 10.1021/ACS.JPCB.5B02980
Fukiko Kubota, Masahiro Goto, Application of ionic liquids to solvent extraction Solvent Extraction Research and Development-japan. ,vol. 13, pp. 23- 36 ,(2006)
Robin D Rogers, Kenneth R Seddon, Ionic Liquids--Solvents of the Future? Science. ,vol. 302, pp. 792- 793 ,(2003) , 10.1126/SCIENCE.1090313
Daphne Depuydt, Liwang Liu, Christ Glorieux, Wim Dehaen, Koen Binnemans, Homogeneous liquid-liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water† Chemical Communications. ,vol. 51, pp. 14183- 14186 ,(2015) , 10.1039/C5CC05649G
Dongbin Zhao, Yongcheng Liao, Ziding Zhang, Toxicity of Ionic Liquids Clean-soil Air Water. ,vol. 35, pp. 42- 48 ,(2007) , 10.1002/CLEN.200600015
Ann E Visser, Scott T Griffin, Deborah H Hartman, Robin D Rogers, Naphthol- and resorcinol-based azo dyes as metal ion complexants in aqueous biphasic systems. Journal of Chromatography B: Biomedical Sciences and Applications. ,vol. 743, pp. 107- 114 ,(2000) , 10.1016/S0378-4347(00)00176-6
Koen Binnemans, Lanthanides and Actinides in Ionic Liquids Chemical Reviews. ,vol. 107, pp. 2592- 2614 ,(2007) , 10.1021/CR050979C
Michiaki Matsumoto, Abhishek Panigrahi, Yuuki Murakami, Kazuo Kondo, Effect of Ammonium- and Phosphonium-Based Ionic Liquids on the Separation of Lactic Acid by Supported Ionic Liquid Membranes (SILMs) Membranes. ,vol. 1, pp. 98- 108 ,(2011) , 10.3390/MEMBRANES1020098
Joan F. Brennecke, Edward J. Maginn, Ionic liquids: Innovative fluids for chemical processing Aiche Journal. ,vol. 47, pp. 2384- 2389 ,(2001) , 10.1002/AIC.690471102
Keith E. Gutowski, Grant A. Broker, Heather D. Willauer, Jonathan G. Huddleston, Richard P. Swatloski, John D. Holbrey, Robin D. Rogers, Controlling the Aqueous Miscibility of Ionic Liquids: Aqueous Biphasic Systems of Water-Miscible Ionic Liquids and Water-Structuring Salts for Recycle, Metathesis, and Separations Journal of the American Chemical Society. ,vol. 125, pp. 6632- 6633 ,(2003) , 10.1021/JA0351802