Reversible Electrochromism in the Thin Films of Single-Transition Metal Phthalocyanines
作者： Naoki Toshima , Shin-ichi Kawamura , Tsuyoshi Tominaga
DOI: 10.1246/CL.1993.1299
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摘要: The reversible electrochromism in the thin films of single-transition metal phthalocyanines is reported. Copper and nickel phthalocyanine can be oxidized rereduced reversibly, when film enough thin, scan range well controlled, appropriate anion used as electrolyte. Especially, cyclic voltammogram a sodium nitrate solution almost Nernstian.
csj.jp参考文章(7)
Alexander. Wolberg, Joost. Manassen, Electrochemical and electron paramagnetic resonance studies of metalloporphyrins and their electrochemical oxidation products Journal of the American Chemical Society. ,vol. 92, pp. 2982- 2991 ,(1970) , 10.1021/JA00713A010
Ru-Jang Lin, Naoki Toshima, Spectroelectrochemistry of New Prussian Blue Films Prepared by a Cast Method Bulletin of the Chemical Society of Japan. ,vol. 64, pp. 136- 148 ,(1991) , 10.1246/BCSJ.64.136
Jack Silver, Peter Lukes, Paul Hey, Mustafa T. Ahmet, Electrochromism in the transition-metal phthalocyanines. Part 2.—Structural changes in and properties of [Cr(pc)] and [Mn(pc)] films J. Mater. Chem.. ,vol. 2, pp. 841- 847 ,(1992) , 10.1039/JM9920200841
Jack Silver, Peter Lukes, Stuart D. Howe, Brendan Howlin, Synthesis, structure, and spectroscopic and electrochromic properties of bis(phthalocyaninato)zirconium(IV) Journal of Materials Chemistry. ,vol. 1, pp. 29- 35 ,(1991) , 10.1039/JM9910100029
G. C. S. Collins, D. J. Schiffrin, The Properties of Electrochromic Film Electrodes of Lanthanide Diphthalocyanines in Ethylene Glycol Journal of The Electrochemical Society. ,vol. 132, pp. 1835- 1842 ,(1985) , 10.1149/1.2114227
Jack Silver, Peter Lukes, Andrew Houlton, Stuart Howe, Paul Hey, Mustafa T. Ahmet, Electrochromism in the transition-metal phthalocyanines. Part 3.—Molecular organisation, reorganisation and assembly under the influence of an applied electric field. Response of [Fe(pc)] and [Fe(pc)Cl] J. Mater. Chem.. ,vol. 2, pp. 849- 855 ,(1992) , 10.1039/JM9920200849
Fu-Ren Fan, Larry R. Faulkner, Phthalocyanine thin films as semiconductor electrodes Journal of the American Chemical Society. ,vol. 101, pp. 4779- 4787 ,(1979) , 10.1021/JA00511A001