Preparation of uranium by electrolysis in chloride melt
作者： K Serrano , P Taxil , O Dugne , S Bouvet , E Puech
DOI: 10.1016/S0022-3115(00)00423-2
关键词:
摘要: The uranium deposits were prepared by electrolysis in a fused chloride melt. Whatever the conditions, deposit morphology was dendritic. influence of parameters current density, melt temperature and electrolyte concentration on investigated using an optimal design. Our results show that increasing makes coatings more compact. dendritic is attributed to transport phenomena (diffusion, convection, migration) promoted cation discharge at substrate-coating interface.
harvard.edu
elsevier.com
sci-hub.se 参考文章(20)
K. Serrano, P. Taxil, Electrochemical reduction of trivalent uranium ions in molten chlorides Journal of Applied Electrochemistry. ,vol. 29, pp. 497- 503 ,(1999) , 10.1023/A:1003402029895
S.L. Marshall, L. Redey, G.F. Vandegrift, D.R. Vissers, Electroformation of uranium hemispherical shells Argonne National Laboratory. ,(1989) , 10.2172/5274651
Joseph J. Katz, Eugene Rabinowitch, The chemistry of uranium : the element,its binary and related compounds Dover Publications. ,(1951)
John M. Huth, Harry L. Swinney, William D. McCormick, Alexander Kuhn, Françoise Argoul, Role of convection in thin-layer electrodeposition Physical Review E. ,vol. 51, pp. 3444- 3458 ,(1995) , 10.1103/PHYSREVE.51.3444
V. Fleury, J.-N. Chazalviel, M. Rosso, Coupling of drift, diffusion, and electroconvection, in the vicinity of growing electrodeposits. Physical Review E. ,vol. 48, pp. 1279- 1295 ,(1993) , 10.1103/PHYSREVE.48.1279
V. Fleury, J. H. Kaufman, D. B. Hibbert, Mechanism of a morphology transition in ramified electrochemical growth Nature. ,vol. 367, pp. 435- 438 ,(1994) , 10.1038/367435A0
D. P. Barkey, D. Watt, Z. Liu, S. Raber, The Role of Induced Convection in Branched Electrodeposit Morphology Selection Journal of The Electrochemical Society. ,vol. 141, pp. 1206- 1212 ,(1994) , 10.1149/1.2054897
F. Argoul, E. Freysz, A. Kuhn, C. Léger, L. Potin, Interferometric characterization of growth dynamics during dendritic electrodeposition of zinc Physical Review E. ,vol. 53, pp. 1777- 1788 ,(1996) , 10.1103/PHYSREVE.53.1777
Terry C Totemeier, Robert D Mariani, Morphologies of uranium and uranium–zirconium electrodeposits Journal of Nuclear Materials. ,vol. 250, pp. 131- 146 ,(1997) , 10.1016/S0022-3115(97)00288-2
George E P Box, Norman R Draper, Empirical Model-Building and Response Surfaces ,(1987)