Polyaniline-derived carbons: Remarkable adsorbents to remove atrazine and diuron herbicides from water.

作者: Jong Min Park , Sung Hwa Jhung

DOI: 10.1016/J.JHAZMAT.2020.122624

关键词:

摘要: Abstract The contamination of water resources by hazardous organic compounds is becoming severe worldwide. In this study, the adsorptive removal atrazine (ATZ) and diuron (DUR), two widely used herbicides, from polyaniline-derived carbons (PDCs) was investigated for first time, under various conditions. A selected PDC, fabricated at optimum conditions, i.e., pyrolysis 800 °C (and labeled PDC(800)), showed remarkable adsorptivity both that is, 7.7 11.3 times maximum adsorption capacity (Q0) ATZ DUR, respectively, compared to activated carbon (AC). Or, Q0 values PDC(800) DUR were 943 884 mg/g, respectively; however, AC only 123 78.0 mg/g, respectively. Moreover, adsorbent had 4.5 3.1 best adsorbent, highest performances, so far, Plausible mechanisms suggested based on porosity in a wide pH range. new reusable via simple solvent washing. Based its performance facile reusability, can be considered promising remove herbicides such as contaminated water.

参考文章(74)
Ana Silvestre-Albero, Joaquin Silvestre-Albero, Manuel Martínez-Escandell, Francisco Rodríguez-Reinoso, Micro/Mesoporous Activated Carbons Derived from Polyaniline: Promising Candidates for CO2 Adsorption Industrial & Engineering Chemistry Research. ,vol. 53, pp. 15398- 15405 ,(2014) , 10.1021/IE5013129
Tawfik A. Saleh, Isotherm, kinetic, and thermodynamic studies on Hg(II) adsorption from aqueous solution by silica- multiwall carbon nanotubes Environmental Science and Pollution Research. ,vol. 22, pp. 16721- 16731 ,(2015) , 10.1007/S11356-015-4866-Z
Patrícia Silva, Sérgio M. F. Vilela, João P. C. Tomé, Filipe A. Almeida Paz, Multifunctional metal–organic frameworks: from academia to industrial applications Chemical Society Reviews. ,vol. 44, pp. 6774- 6803 ,(2015) , 10.1039/C5CS00307E
A. G. Slater, A. I. Cooper, Function-led design of new porous materials Science. ,vol. 348, ,(2015) , 10.1126/SCIENCE.AAA8075
R.T. Carneiro, T. Taketa, R.J. Gomes Neto, J.L. Oliveira, E.V. Campos, M. Moraes, C.M. Silva, M. Beppu, L.F. Fraceto, Removal of glyphosate herbicide from water using biopolymer membranes. Journal of Environmental Management. ,vol. 151, pp. 353- 360 ,(2015) , 10.1016/J.JENVMAN.2015.01.005
Guiyin Xu, Bing Ding, Ping Nie, Laifa Shen, Jie Wang, Xiaogang Zhang, Porous nitrogen-doped carbon nanotubes derived from tubular polypyrrole for energy-storage applications. Chemistry: A European Journal. ,vol. 19, pp. 12306- 12312 ,(2013) , 10.1002/CHEM.201301352
Nazmul Abedin Khan, Zubair Hasan, Sung Hwa Jhung, Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): A review Journal of Hazardous Materials. ,vol. 244-245, pp. 444- 456 ,(2013) , 10.1016/J.JHAZMAT.2012.11.011
Zubair Hasan, Eun-Jeong Choi, Sung Hwa Jhung, Adsorption of naproxen and clofibric acid over a metal–organic framework MIL-101 functionalized with acidic and basic groups Chemical Engineering Journal. ,vol. 219, pp. 537- 544 ,(2013) , 10.1016/J.CEJ.2013.01.002
Grigorios Kyriakopoulos, Danae Doulia, Adsorption of Pesticides on Carbonaceous and Polymeric Materials from Aqueous Solutions: A Review Separation and Purification Reviews. ,vol. 35, pp. 97- 191 ,(2006) , 10.1080/15422110600822733