Silicon-containing alka-1,3-dienes and their functional derivatives in organic synthesis

摘要: Data on the synthesis and chemical reactions of silicon-containing 1,3-dienes are surveyed for first time in present review. It is shown that addition 1- 2-triorganosilylalka-1,3-dienes their derivatives most interesting promising fine organic synthesis. The application trialkylsilyl group as a protecting new reaction centre, which makes it possible to obtain carbon–carbon or carbon–heteroatom bonds, examined. has been found double bonds remote from silicon atom reactive regardless nature reagent attacking species always binds terminal carbon buta-1,3-diene fragment. bibliography includes 329 references.