High alcohol synthesis from CO and H2on ruthenium catalysts
作者： Yu-Wen Chen
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摘要: A Ru/MoO2 catalyst was found to be active for the synthesis gas conversion straight chain primary alcohols. Potassium carbonate effective enhancing high alcohol formation. The carbon number distribution of alcoholic products followed Anderson-Schulz-Flory which gave growth probabilities 0.27–0.35. In addition, catalysts are significantly more sulfur resistant than a Ru/Al2O3 catalyst. higher resistance these is mainly due their adsorption capacities. Le catalyseur s'est avere actif pour la du gaz de synthese en alcools primaires chaǐnes lineaires. Le potassium est efficace augmenter formation des superieurs. La nombre carbones dans les produits alcooliques suit Flory-Schulz-Anderson avec probabilites croissance 0,27 0,35. De plus, catalyseurs sont beaucoup plus resistants au soufre que le Ru/Al2O3. Cette grande imputable principalement une capacite d'adsorption soufre.
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