摘要: Tip-enhanced Raman spectroscopy is a vibrational with hitherto unprecedented sensitivity and spatial resolution. Since the enhancement mainly provided by near-field excited at apex of suitable tip, TERS appears to be widely applicable microscopy tool, in contrast its parents, surface-enhanced (SERS) scanning optical (SNOM). TER scattering has been observed for number molecules adsorbed various substrates, including single-crystalline metal surfaces, showing thereby more than million-fold scattering. It important note that field-enhancement provides, beyond TERS, promising avenues applications other techniques, such as tip-enhanced CARS, two-photon fluorescence infrared scattering-type microscopy.
springer.com
mpg.de
harvard.edu
springerlink.com参考文章(66)
D. L. Mills, Theory of STM-induced enhancement of dynamic dipole moments on crystal surfaces Physical Review B. ,vol. 65, pp. 125419- ,(2002) , 10.1103/PHYSREVB.65.125419
Raoul M. Stöckle, Yung Doug Suh, Volker Deckert, Renato Zenobi, Nanoscale chemical analysis by tip-enhanced Raman spectroscopy Chemical Physics Letters. ,vol. 318, pp. 131- 136 ,(2000) , 10.1016/S0009-2614(99)01451-7
D. Mehtani, N. Lee, R. D. Hartschuh, A. Kisliuk, M. D. Foster, A. P. Sokolov, J. F. Maguire, Nano-Raman spectroscopy with side-illumination optics Journal of Raman Spectroscopy. ,vol. 36, pp. 1068- 1075 ,(2005) , 10.1002/JRS.1409
Dehong Hu, Miodrag Micic, Nicholas Klymyshyn, Yung Doug Suh, H. Peter Lu, Correlated topographic and spectroscopic imaging beyond diffraction limit by atomic force microscopy metallic tip-enhanced near-field fluorescence lifetime microscopy Review of Scientific Instruments. ,vol. 74, pp. 3347- 3355 ,(2003) , 10.1063/1.1581359
Katrin Kneipp, Yang Wang, Harald Kneipp, Lev T. Perelman, Irving Itzkan, Ramachandra R. Dasari, Michael S. Feld, Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS) Physical Review Letters. ,vol. 78, pp. 1667- 1670 ,(1997) , 10.1103/PHYSREVLETT.78.1667
B. Pettinger, A. Gerolymatou, Dyes Adsorbed at Ag-Colloids: Substitution of Fluorescence by Similarly Efficient Surface Fluorescence and Surface Raman Scattering Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 88, pp. 359- 363 ,(1984) , 10.1002/BBPC.19840880409
G. Binnig, N. Garcia, H. Rohrer, Conductivity sensitivity of inelastic scanning tunneling microscopy Physical Review B. ,vol. 32, pp. 1336- 1338 ,(1985) , 10.1103/PHYSREVB.32.1336
J. I. Pascual, J. Gómez-Herrero, D. Sánchez-Portal, H.-P. Rust, Vibrational spectroscopy on single C60 molecules: The role of molecular orientation Journal of Chemical Physics. ,vol. 117, pp. 9531- 9534 ,(2002) , 10.1063/1.1524155
Markus B. Raschke, Leopoldo Molina, Thomas Elsaesser, Dong Ha Kim, Wolfgang Knoll, Karsten Hinrichs, Apertureless near-field vibrational imaging of block-copolymer nanostructures with ultrahigh spatial resolution ChemPhysChem. ,vol. 6, pp. 2197- 2203 ,(2005) , 10.1002/CPHC.200500218
Ioan Notingher, Alistair Elfick, Effect of sample and substrate electric properties on the electric field enhancement at the apex of SPM nanotips. Journal of Physical Chemistry B. ,vol. 109, pp. 15699- 15706 ,(2005) , 10.1021/JP0523120