Zeeman effect in the Q-band absorption spectrum of palladiumporphin in an n-octane single crystal
作者： G.W. Canters , M. Noort , J.H. van der Waals
DOI: 10.1016/0009-2614(75)85484-4
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摘要: Abstract The Zeeman effect in the high resolution spectrum of palladiumporphin a single crystal n-octane at 4.2 K is reported. two zero-point vibronic components |x〉 and |y〉 state S1 are split by 30 cm−1. They show large second order from which one derives |〈x|Lz|y〉| ⩾ 4.4 |h. In field energy component shows broadening proportional to H2.
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