A versatile synthesis of a new bisiminophosphorane
作者： Andreea Micle , Natalia Miklášova , Richard A Varga , Aurelia Pascariu , Nicoleta Pleşu
DOI: 10.1016/J.TETLET.2009.07.112
关键词:
摘要: Abstract The iminophosphorane CH2CH2[P{ NP( O)(OPh)2}Ph2]2 is synthesized in high yields (80–97%) via a very convenient procedure using diphenylphosphoryl azide (DPPA) and 1,2-bis(diphenylphosphino)ethane.
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sci-hub.se 参考文章(32)
A. William Johnson, Ylides and imines of phosphorus ,(1993)
K. Ninomiya, T. Shioiri, S. Yamada, Phosphorus in organic synthesis—VII Tetrahedron. ,vol. 30, pp. 2151- 2157 ,(1974) , 10.1016/S0040-4020(01)97352-1
Klaus Bartel, Konrad v. Werner, Wolfgang Beck, Pseudohalogenometallverbindungen: LVIII. Reaktionen von diphenylphosphorylazid und perfluor-n-hexylsulfonylazid mit triphenylphosphan-komplexen von platin(0), rhodium(I), iridium(I), ruthenium(0), kobalt(II) und kupfer(I) Journal of Organometallic Chemistry. ,vol. 243, pp. 79- 85 ,(1983) , 10.1016/0022-328X(83)80223-X
P. Imhoff, R. Van Asselt, C. J. Elsevier, K. Vrieze, K. Goubitz, K. F. Van Malssen, C. H. Stam, SYNTHESIS, STRUCTURE AND REACTIVITY OF BIS(N-ARYL-IMINOPHOSPHORANYL)METHANES. X-RAY CRYSTAL STRUCTURES OF (4-CH3-C6H4-N˭PPh2)2CH2 AND (4-NO2-C6H4-N˭PPh2)2CH2 Phosphorus Sulfur and Silicon and The Related Elements. ,vol. 47, pp. 401- 415 ,(1990) , 10.1080/10426509008037996
Ramalingam Venkateswaran, Maravanji S. Balakrishna, Shaikh M. Mobin, The Iminophosphorane‐Phosphane Ph2PC6H4OC6H4PPh2=NP(O)(OPh)2: Synthesis, Reactivity, and Catalytic Activity in Suzuki Cross‐Coupling and the Homogeneous Hydrogenation of Olefins European Journal of Inorganic Chemistry. ,vol. 2007, pp. 1930- 1938 ,(2007) , 10.1002/EJIC.200601126
Takayuki Shioiri, Kunihiro Ninomiya, Shunichi Yamada, Diphenylphosphoryl azide. A new convenient reagent for a modified Curtus reaction and for the peptide synthesis. Journal of the American Chemical Society. ,vol. 94, pp. 6203- 6205 ,(1972) , 10.1021/JA00772A052
Stefan Bräse, Carmen Gil, Kerstin Knepper, Viktor Zimmermann, Organic Azides: An Exploding Diversity of a Unique Class of Compounds Angewandte Chemie. ,vol. 44, pp. 5188- 5240 ,(2005) , 10.1002/ANIE.200400657
Elena Vismara, Marco Serravalle, Francesco Minisci, Polar effects in free-radical reactions: new selective alkylations of heteroaromatic bases by benzoylperoxide and olefins Tetrahedron Letters. ,vol. 27, pp. 3187- 3190 ,(1986) , 10.1016/S0040-4039(00)84750-4
Andrew S. Thompson, Guy R. Humphrey, Anthony M. DeMarco, David J. Mathre, Edward J. J. Grabowski, Direct conversion of activated alcohols to azides using diphenyl phosphorazidate. A practical alternative to mitsunobu conditions Journal of Organic Chemistry. ,vol. 58, pp. 5886- 5888 ,(1993) , 10.1021/JO00074A008
Maravanji S. Balakrishna, S. Teipel, A. Alan Pinkerton, Ronald G. Cavell, New silylated iminophosphorano(amino)phosphines Me(3)SiN=PPh(2)N(R)PPh(2) (R = Et, (n)Pr, (n)Bu). Crystal and molecular structure of trimethylsilyliminophosphorano(propylamino)diphenylphosphine Me(3)SiN=PPh(2)N((n)Pr)PPh(2). Further oxidative derivatization with S, Se, and azides, titanium(IV) transmetalation of the imine, and syntheses of rhodium(I), palladium(II), and platinum(II) complexes of these iminophosphorano(amino)phosphines. Inorganic Chemistry. ,vol. 40, pp. 1802- 1808 ,(2001) , 10.1021/IC000878R