Synthesis of poly (n-butyl acrylates) by a novel microemulsion polymerization for PSAs applications

作者: Lei Zhang , Yingjie Cao , Su Wang , Zbigniew Czech , Lu Shao

DOI: 10.1016/J.IJADHADH.2013.09.038

关键词:

摘要: Abstract Pressure sensitive adhesives (PSAs) are the adhesive materials that can provide strong adhesion to solid surfaces under a light contact pressure for short time. A novel microemulsion polymerization was established obtain high properties of PSA on basis poly (n-butyl acrylates) (PBA). Stable PBA with solids content had been synthesized. Z-average size could be smaller than 20 nm anionic emulsifier N4SES-AQ. FT-IR spectra showed C=C contained in monomers gone through reaction. The result DSC testing n-butyl acrylate (BA) and acrylic acid (AA) were well copolymerized. good performance reached when N4SES-AQ is 0.5 wt% 180° peel strength reach 680.1 N/m. tapes produced from resulting suitable practical applications.

参考文章(18)
Zbigniew Czech, Katarzyna Wilpiszewska, Bożena Tyliszczak, Xu Jiang, Yongping Bai, Lu Shao, Biodegradable self-adhesive tapes with starch carrier International Journal of Adhesion and Adhesives. ,vol. 44, pp. 195- 199 ,(2013) , 10.1016/J.IJADHADH.2013.03.002
C. Plessis, G. Arzamendi, M. Agnely, J. R. Leiza, J. M. Asua, Seeded semibatch emulsion polymerization ofn-butyl acrylate: Effect of the seed properties Journal of Polymer Science Part A. ,vol. 40, pp. 2878- 2883 ,(2002) , 10.1002/POLA.10375
Klaus Tauer, Alberto G. Ramírez, Raúl G. López, Effect of the surfactant concentration on the kinetics of oil in water microemulsion polymerization: a case study with butyl acrylate Comptes Rendus Chimie. ,vol. 6, pp. 1245- 1266 ,(2003) , 10.1016/J.CRCI.2003.06.008
Zbigniew Czech, New generation of crosslinking agents based on multifunctional methylaziridines International Journal of Adhesion and Adhesives. ,vol. 27, pp. 49- 58 ,(2007) , 10.1016/J.IJADHADH.2005.12.003
A. Marçais, E. Papon, J.-J. Villenave, Ph. Tordjeman, R. Pirri, P., Gérard, Tack properties of methyl methacrylate and 2‐ethylhexyl acrylate emulsion copolymers: influence of the polymerisation process Macromolecular Symposia. ,vol. 151, pp. 497- 502 ,(2000) , 10.1002/1521-3900(200002)151:1<497::AID-MASY497>3.0.CO;2-5
Víctor M. Ovando-Medina, René D. Peralta, Eduardo Mendizábal, Hugo Martínez-Gutiérrez, Miguel A. Corona-Rivera, Microemulsion copolymerization of vinyl acetate and butyl acrylate using a mixture of anionic and non-ionic surfactants Polymer Bulletin. ,vol. 66, pp. 133- 146 ,(2011) , 10.1007/S00289-010-0314-X
Zbigniew Czech, New copolymerizable photoinitiators for radiation curing of acrylic PSA International Journal of Adhesion and Adhesives. ,vol. 27, pp. 195- 199 ,(2007) , 10.1016/J.IJADHADH.2005.10.003
Gurutze Arzamendi, Jose Ramon Leiza, Molecular Weight Distribution (Soluble and Insoluble Fraction) in Emulsion Polymerization of Acrylate Monomers by Monte Carlo Simulations Industrial & Engineering Chemistry Research. ,vol. 47, pp. 5934- 5947 ,(2008) , 10.1021/IE701752F
Jie Zhu, Xiaoyan Zhang, Feng Gao, Ming Chen, Shiqiang Huang, Preparation and properties of alkoxysilane/acrylate copolymer microemulsion Journal of Polymer Research. ,vol. 18, pp. 1991- 1997 ,(2011) , 10.1007/S10965-011-9606-6