Structural chemistry of organotin carboxylates: XVI. Structural variation in dicarboxylato tetraorganostannoxanes: Crystal structrure of {[Me2Sn(O2CC4H3S)]2O}2☆

作者: C. Vasta , V.K. Jain , T.K. Das , Edward R.T. Tiekink

DOI: 10.1016/0022-328X(91)86428-S

关键词:

摘要: Abstract The cyrstal structure of the title compound shows that it has usual dicarboxylato tetraorganodistannoxane structure, based on a centrosymmetric Sn 2 O unit connected to exocyclic atoms via two bridging carboxylate ligands; remaining ligands are coordinated exocylic atom in monodentate mode. There no significant contacts between and S atoms.

参考文章(8)
C.S. Parulekar, V.K. Jain, T.K. Das, A.R. Gupta, B.F. Hoskins, E.R.T. Tiekink, Structural chemistry of organotin carboxylates: II. The crystal structure of the dicarboxylato tetraorganodistannoxane:{sunBu2Sn(O2CC5H4N)]2O}2 Journal of Organometallic Chemistry. ,vol. 372, pp. 193- 199 ,(1989) , 10.1016/0022-328X(89)87093-7
Gurmit K. Sandhu, Neelam Sharma, Edward R.T. Tiekink, Structural chemistry of organotin carboxylates Journal of Organometallic Chemistry. ,vol. 403, pp. 119- 131 ,(1991) , 10.1016/0022-328X(91)83093-J
Thomas P. Lockhart, William F. Manders, Elizabeth M. Holt, Solution and solid-state molecular structures of Me2Sn(OAc)2 and its hydrolyzate, ([Me2Sn(OAc)]2O)2, by solution and solid-state carbon-13 NMR. X-ray diffraction study of the hydrolyzate Journal of the American Chemical Society. ,vol. 108, pp. 6611- 6616 ,(1986) , 10.1021/JA00281A026
Ionel Haiduc, Cristian Silvestru, Metal compounds in cancer chemotherapy Coordination Chemistry Reviews. ,vol. 99, pp. 253- 296 ,(1990) , 10.1016/0010-8545(90)80065-2
V. Chandrasekhar, Roberta O. Day, Joan M. Holmes, Robert R. Holmes, Mononuclear and tetranuclear diorganotin(IV) carboxylates from the reaction of dimethyltin oxide with anthranilic acid and its p-amino isomer Inorganic Chemistry. ,vol. 27, pp. 958- 964 ,(1988) , 10.1021/IC00278A044
Edward R T Tiekink, Structural chemistry of organotin carboxylates: a review of the crystallographic literature Applied Organometallic Chemistry. ,vol. 5, pp. 1- 23 ,(1991) , 10.1002/AOC.590050102