Accelerated degradation of Polyetheretherketone (PEEK) composite materials for recycling applications
作者： L.O. Dandy , G. Oliveux , J. Wood , M.J. Jenkins , G.A. Leeke
DOI: 10.1016/J.POLYMDEGRADSTAB.2014.12.012
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摘要: Abstract The decomposition of Polyetheretherketone (PEEK) is carried out at 623 K within 30 min using a co-solvent system comprising ethanol and water. It has not previously been possible to carryout the PEEK below 703 K in aqueous media. Decomposition achieved catalytic quantities caesium carbonate (Cs 2 CO 3 ), as low 19 μmol ml −1 , high pressure bomb reactor. Carbon fibres are separated from PEEK/carbon fibre composite analysed by SEM-EDX. A reaction scheme proposed for process, producing phenol dibenzofuran major products. Phenol quantitatively means HPLC, identification products performed GC–MS. 7 K above its melt temperature Generally Recognised Safe (GRAS) solvents represents significant advance recycling end-of-life, contaminated deteriorated thermoplastic materials.
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sci-hub.se 参考文章(28)
Steven M. Kurtz, Chemical and Radiation Stability of PEEK PEEK Biomaterials Handbook. pp. 75- 79 ,(2012) , 10.1016/B978-1-4377-4463-7.10006-5
Oliver S. Fleming, Sergei G. Kazarian, Polymer Processing with Supercritical Fluids John Wiley & Sons, Ltd. pp. 205- 238 ,(2006) , 10.1002/3527606726.CH10
Ana M. Díez-Pascual, Gerardo Martínez, Marián A. Gómez, Synthesis and Characterization of Poly(ether ether ketone) Derivatives Obtained by Carbonyl Reduction Macromolecules. ,vol. 42, pp. 6885- 6892 ,(2009) , 10.1021/MA901208E
Yoko Shibasaki, Jun-ichi Kadokawa, Hideyuki Tagaya, Bunpei Hatano, Chie Kato, Decomposition reactions of epoxy resin and polyetheretherketone resin in sub- and supercritical water Journal of Material Cycles and Waste Management. ,vol. 6, pp. 1- 5 ,(2004) , 10.1007/S10163-003-0098-2
Andreas Schieber, Petra Keller, Reinhold Carle, Determination of phenolic acids and flavonoids of apple and pear by high-performance liquid chromatography. Journal of Chromatography A. ,vol. 910, pp. 265- 273 ,(2001) , 10.1016/S0021-9673(00)01217-6
Ingo Leusbrock, Sybrand J. Metz, Glenn Rexwinkel, Geert F. Versteeg, The solubilities of phosphate and sulfate salts in supercritical water Journal of Supercritical Fluids. ,vol. 54, pp. 1- 8 ,(2010) , 10.1016/J.SUPFLU.2010.03.003
M.S Khan, S.N Rogak, Solubility of Na2SO4, Na2CO3 and their mixture in supercritical water Journal of Supercritical Fluids. ,vol. 30, pp. 359- 373 ,(2004) , 10.1016/J.SUPFLU.2003.09.012
C Vacogne, R Wise, Joining of high performance carbon fibre/PEEK composites Science and Technology of Welding and Joining. ,vol. 16, pp. 369- 376 ,(2011) , 10.1179/1362171811Y.0000000027
Ingo Leusbrock, Sybrand J. Metz, Glenn Rexwinkel, Geert F. Versteeg, The solubility of magnesium chloride and calcium chloride in near-critical and supercritical water Journal of Supercritical Fluids. ,vol. 53, pp. 17- 24 ,(2010) , 10.1016/J.SUPFLU.2009.12.015
K. Y. Kim, C. Lee, B. H. Ryu, Dielectric Relaxation Behavior of PEEK during the Loss of the Coolant Accident ieee international conference on solid dielectrics. pp. 98- 101 ,(2007) , 10.1109/ICSD.2007.4290762