The use of trimethylsilyl ethers in the characterization of natural sterols and steroid diols by gas chromatography-mass spectrometry
作者： C.J.W. Brooks , W. Henderson , G. Steel
DOI: 10.1016/0005-2760(73)90101-X
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摘要: Abstract Trimethylsilyl ethers of 16 sterols, six cholestanediols, cholestenediols and a cholestanetriol have been examined by combined gas chromatography-mass spectrometry. Characteristic features the data are discussed in relation to previous work, examples given use technique identification naturally-occurring steroids.
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sci-hub.se 参考文章(28)
E.C. HORNING, C.J.W. BROOKS, W.J.A. VANDEN HEUVEL, Gas Phase Analytical Methods for the Study of Steroids Advances in lipid research. ,vol. 6, pp. 273- 392 ,(1968) , 10.1016/B978-1-4831-9942-9.50014-0
Peter Eneroth, Kjell Hellström, Ragnar Ryhage, Identification of two neutral metabolites of stigmasterol found in human feces Steroids. ,vol. 6, pp. 707- 720 ,(1965) , 10.1016/0039-128X(65)90095-4
John Diekman, Carl Djerassi, Mass spectrometry in structural and stereochemical problems. CXXV - Mass spectrometry of some steroid trimethylsilyl ethers. Journal of Organic Chemistry. ,vol. 32, pp. 1005- 1012 ,(1967) , 10.1021/JO01279A033
P ENEROTH, E NYSTROM, Sterol composition of the steryl sulfate fraction in human fecesBile acids and steroids 196 Steroids. ,vol. 11, pp. 417- 427 ,(1968) , 10.1016/S0039-128X(68)80059-5
B. E. Gustafsson, J.-Å. Gustafsson, J. Sjövall, J. H. Bowie, D. H. Williams, E. Bunnenberg, Carl Djerassi, Ruth Records, Intestinal and fecal sterols in germfree and conventional rats. Bile acids and steroids 172. Acta Chemica Scandinavica. ,vol. 20, pp. 1827- 1835 ,(1966) , 10.3891/ACTA.CHEM.SCAND.20-1827
GORDON STEEL, WILLIAM HENDERSON, Isolation and Characterization of Stanols from the Green River Shale Nature. ,vol. 238, pp. 148- 150 ,(1972) , 10.1038/238148A0
J.-A. Gustafsson, J. Sjovall, Identification of 22‐, 24‐ and 26‐Hydroxycholesterol in the Steroid Sulphate Fraction of Faeces from Infants FEBS Journal. ,vol. 8, pp. 467- 472 ,(1969) , 10.1111/J.1432-1033.1969.TB00550.X
T. Luukkainen, W.J.A. VandenHeuvel, E.O.A. Haahti, E.C. Horning, Gas-chromatographic behavior of trimethylsilyl ethers of steroids Biochimica et Biophysica Acta. ,vol. 52, pp. 599- 601 ,(1961) , 10.1016/0006-3002(61)90426-7
C. J. W. Brooks, G. Steel, W. A. Harland, Lipids of human atheroma VI. Hydrocarbons of the atheromatous plaque Lipids. ,vol. 5, pp. 818- 824 ,(1970) , 10.1007/BF02531974
E. M. Chambaz, E. C. Horning, Steroid Trime Thylsilyl Ethers Analytical Letters. ,vol. 1, pp. 201- 211 ,(1967) , 10.1080/00032716708051119