Recovery of vanillin from lignin/vanillin mixture by using tubular ceramic ultrafiltration membranes

作者: M. Žabková , E.A. Borges da Silva , A.E. Rodrigues

DOI: 10.1016/J.MEMSCI.2007.06.025

关键词:

摘要: Abstract The aim of this work is to evaluate the membrane ultrafiltration process for recovery vanillin from Kraft lignin oxidation media. Tubular ceramic membranes with molecular weight ( M w ) cut-off 1, 5 and 15 kDa are investigated. influence concentration pH mixture on performance studied in batch mode. Permeate flux, content retentate permeate streams were measured. A theoretical model used calculate variation profile within polarization layer estimate surface during operation. values obtained at suggests that there a growth gel higher operating conditions used. By filtrating lignin/vanillin 60/6 g L −1 12.5 using 1 kDa membrane, observed rejection was 0.972. On other hand, small leads significant decline flux compared larger cut-off. It very high cleaning efficiency can be sodium hydroxide solution.

参考文章(63)
Lignin: properties and materials. American Chemical Society. ,(1989) , 10.1021/BK-1989-0397
Ayiguli Keyoumu, Ragnar Sjödahl, Gunnar Henriksson, Monica Ek, Göran Gellerstedt, Mikael E. Lindström, Continuous Nano- and Ultrafiltration of Kraft Pulping Black Liquor with Ceramic Filters : A method for lowering the load on the recovery boiler while generating valuable side-products Industrial Crops and Products. ,vol. 20, pp. 143- 150 ,(2004) , 10.1016/J.INDCROP.2004.04.017
M. C. Porter, Concentration Polarization with Membrane Ultrafiltration Industrial & Engineering Chemistry Product Research and Development. ,vol. 11, pp. 234- 248 ,(1972) , 10.1021/I360043A002
Simo Sarkanen, David C. Teller, Clyde R. Stevens, Joseph L. McCarthy, Lignin. 20. Associative interactions between kraft lignin components Macromolecules. ,vol. 17, pp. 2588- 2597 ,(1984) , 10.1021/MA00142A022
A.S. Grandison, M.J. Lewis, Separation processes in the food and biotechnology industries: Principles and applications Filtration & Separation. ,vol. 33, pp. 524- ,(1996) , 10.1016/S0015-1882(96)90089-0
SIRSHENDU DE, JENNIFER M. DIAS, P. K. BHATTACHARYA, SHORT AND LONG TERM FLUX DECLINE ANALYSIS IN ULTRAFILTRATION Chemical Engineering Communications. ,vol. 159, pp. 67- 89 ,(1997) , 10.1080/00986449708936594
Ingmar H. Huisman, Eert Vellenga, Gun Trägårdh, Christian Trägårdh, The influence of the membrane zeta potential on the critical flux for crossflow microfiltration of particle suspensions Journal of Membrane Science. ,vol. 156, pp. 153- 158 ,(1999) , 10.1016/S0376-7388(98)00328-7
S TU, V RAVINDRAN, M PIRBAZARI, A pore diffusion transport model for forecasting the performance of membrane processes Journal of Membrane Science. ,vol. 265, pp. 29- 50 ,(2005) , 10.1016/J.MEMSCI.2005.04.051
Danielle R. Robert, Michel Bardet, Göran Gellerstedt, Eva Lisa Lindfors, Structural Changes in Lignin During Kraft Cooking Part 3. On the Structure of Dissolved Lignins Journal of Wood Chemistry and Technology. ,vol. 4, pp. 239- 263 ,(1984) , 10.1080/02773818408070647