Benzylamine-directed growth of olivine-type LiMPO4 nanoplates by a supercritical ethanol process for lithium-ion batteries
作者： Quang Duc Truong , Murukanahally Kempaiah Devaraju , Itaru Honma
DOI: 10.1039/C4TA03566F
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摘要: Olivine-type LiMPO4 (M = Fe, Mn, Co and Ni) cathode materials hold promise for next-generation of lithium-ion batteries future applications as hybrid electric vehicles or vehicles. In lithium intercalation olivine compounds, the diffusion along a channel is highly anisotropic which mainly confined to [010] direction. Thus, nanosheets nanoplates with shortened Li ion distance direction are enabled accelerate rate improve power density batteries. Herein, we report production high-quality thin exposed {010} facets by rapid supercritical fluid processing. The unique structure nanocrystals pathway allows fast extraction/insertion ions in structures. provide high capacity excellent cyclability.
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