Local structure and polaron formation in La1−xCaxMnO3

作者: R.G DiFrancesco , S.J.L Billinge , G.H Kwei , J.J Neumeier , J.D Thompson

DOI: 10.1016/S0921-4526(97)00608-X

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摘要: Abstract The local structure of La1−xCaxMnO3 is determined from pair-distribution function (PDF) analysis pulsed neutron diffraction. We have compared the effect on crossing metal-insulator transition as a temperature and composition. Crossing boundary at low by varying composition yields similar distortions to those seen in dependence indicating presence polarons insulating phase which disappear metallic phase.

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