The electrochemical catalytic activity of single-walled carbon nanotubes towards VO2+/VO2+ and V3+/V2+ redox pairs for an all vanadium redox flow battery

作者: Wenyue Li , Jianguo Liu , Chuanwei Yan , None

DOI: 10.1016/J.ELECTACTA.2012.06.109

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摘要: Single-walled carbon nanotube (SWCNT) was used as an electrode catalyst for an all vanadium redox flow battery (VRFB). The electrochemical property of SWCNT towards VO2+/VO2+ and V3+/V2+ was carefully characterized by cyclic voltammetric (CV) and electrochemical impedance spectroscopy (EIS) measurements. The peak current values for these redox pairs were significantly higher on the modified glassy carbon electrode compared with those obtained on the bare electrode, suggesting the excellent …

参考文章(22)
Jing-Hong Zhou, Zhi-Jun Sui, Jun Zhu, Ping Li, De Chen, Ying-Chun Dai, Wei-Kang Yuan, Characterization of surface oxygen complexes on carbon nanofibers by TPD, XPS and FT-IR Carbon. ,vol. 45, pp. 785- 796 ,(2007) , 10.1016/J.CARBON.2006.11.019
Jia-Xin Li, Yi Zhao, Lun-Hui Guan, Lithium storage in single-walled carbon nanotubes Electrochemistry Communications. ,vol. 12, pp. 592- 595 ,(2010) , 10.1016/J.ELECOM.2010.02.007
Tao Wu, Kelong Huang, Suqin Liu, Shuxin Zhuang, Dong Fang, Sha Li, Dan Lu, Anqun Su, Hydrothermal ammoniated treatment of PAN-graphite felt for vanadium redox flow battery Journal of Solid State Electrochemistry. ,vol. 16, pp. 579- 585 ,(2012) , 10.1007/S10008-011-1383-Y
Pengxian Han, Yanhua Yue, Zhihong Liu, Wei Xu, Lixue Zhang, Hongxia Xu, Shanmu Dong, Guanglei Cui, Graphene oxide nanosheets/multi-walled carbon nanotubes hybrid as an excellent electrocatalytic material towards VO2+/VO2+ redox couples for vanadium redox flow batteries Energy and Environmental Science. ,vol. 4, pp. 4710- 4717 ,(2011) , 10.1039/C1EE01776D
E. Sum, M. Skyllas-Kazacos, A study of the V(II)/V(III) redox couple for redox flow cell applications Journal of Power Sources. ,vol. 15, pp. 179- 190 ,(1985) , 10.1016/0378-7753(85)80071-9
Stephen Brunauer, P. H. Emmett, Edward Teller, Adsorption of Gases in Multimolecular Layers Journal of the American Chemical Society. ,vol. 60, pp. 309- 319 ,(1938) , 10.1021/JA01269A023
E. Sum, M. Rychcik, M. Skyllas-kazacos, Investigation of the V(V)/V(IV) system for use in the positive half-cell of a redox battery Journal of Power Sources. ,vol. 16, pp. 85- 95 ,(1985) , 10.1016/0378-7753(85)80082-3