Studies on reactivity of polymers—I. Chlorination of poly(vinyl chloride) using sulphuryl chloride in solution in the presence of radical initiators
作者： R.T. Sikorski , E. Czerwińska
DOI: 10.1016/0014-3057(86)90115-1
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摘要: Abstract The chlorination of poly(vinyl chloride) with sulphuryl chloride in solution the presence azobisisobutyronitrile has been studied. microstructure product is similar to that products by gaseous chlorine. rate constant and activation energy methylene group grouping -CHCl-CH 2 -CHCl- have determined.
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